Synthesis, Characterization and Corrosion Protective Efficiency of 2[2-Oxo-phenyl hydrazinyl ethyl] benzamide on Mild Steel in Sulphuric Acid Medium
2[2-Oxo-phenyl hydrazinyl ether] benzamide (2BA) was synthesized, characterized and tested effective for corrosion inhibition of mild steel in 1 N H2SO4 solution using galvanodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. Polarization resistances calculated from th...
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| Format: | Article |
| Language: | English |
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Wiley
2010-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2010/402878 |
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| author | Rinki Goel Weqar A. Siddiqi V. M. Chaubey Bahar Ahmed |
| author_facet | Rinki Goel Weqar A. Siddiqi V. M. Chaubey Bahar Ahmed |
| author_sort | Rinki Goel |
| collection | DOAJ |
| description | 2[2-Oxo-phenyl hydrazinyl ether] benzamide (2BA) was synthesized, characterized and tested effective for corrosion inhibition of mild steel in 1 N H2SO4 solution using galvanodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. Polarization resistances calculated from the EIS measurements are in good agreement with those obtained from alternating current (AC) polarization measurements. The mild steel samples were also analyzed by Scanning Electron Microscopy (SEM). The result showed that 2BA is an excellent inhibitor for mild steel in acid medium. The inhibition was assumed to occur via adsorption of the inhibitor molecule on the metal surface. In the 303-323K temperature range, the 2BA adsorption follows Langmuir isotherm model. The protection efficiency increases with increasing the inhibitor concentration in the range of 250-1000 ppm but slightly decreases with increasing temperature. |
| format | Article |
| id | doaj-art-fdaef2c3a34d44119ec4e3a4d5a1f9b0 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2010-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-fdaef2c3a34d44119ec4e3a4d5a1f9b02025-02-03T05:47:58ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-017233134010.1155/2010/402878Synthesis, Characterization and Corrosion Protective Efficiency of 2[2-Oxo-phenyl hydrazinyl ethyl] benzamide on Mild Steel in Sulphuric Acid MediumRinki Goel0Weqar A. Siddiqi1V. M. Chaubey2Bahar Ahmed3Department of Applied Science & Humanities, Faculty of Engineering and Technology, Jamia Millia Islamia, New Delhi-110025, IndiaDepartment of Applied Science & Humanities, Faculty of Engineering and Technology, Jamia Millia Islamia, New Delhi-110025, IndiaDepartment of Applied Science & Humanities, Faculty of Engineering and Technology, Jamia Millia Islamia, New Delhi-110025, IndiaDepartment of Pharmaceutical Chemistry, Faculty of Pharmacy, Jamia Hamdard, New Delhi-110025, India2[2-Oxo-phenyl hydrazinyl ether] benzamide (2BA) was synthesized, characterized and tested effective for corrosion inhibition of mild steel in 1 N H2SO4 solution using galvanodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. Polarization resistances calculated from the EIS measurements are in good agreement with those obtained from alternating current (AC) polarization measurements. The mild steel samples were also analyzed by Scanning Electron Microscopy (SEM). The result showed that 2BA is an excellent inhibitor for mild steel in acid medium. The inhibition was assumed to occur via adsorption of the inhibitor molecule on the metal surface. In the 303-323K temperature range, the 2BA adsorption follows Langmuir isotherm model. The protection efficiency increases with increasing the inhibitor concentration in the range of 250-1000 ppm but slightly decreases with increasing temperature.http://dx.doi.org/10.1155/2010/402878 |
| spellingShingle | Rinki Goel Weqar A. Siddiqi V. M. Chaubey Bahar Ahmed Synthesis, Characterization and Corrosion Protective Efficiency of 2[2-Oxo-phenyl hydrazinyl ethyl] benzamide on Mild Steel in Sulphuric Acid Medium E-Journal of Chemistry |
| title | Synthesis, Characterization and Corrosion Protective Efficiency of 2[2-Oxo-phenyl hydrazinyl ethyl] benzamide on Mild Steel in Sulphuric Acid Medium |
| title_full | Synthesis, Characterization and Corrosion Protective Efficiency of 2[2-Oxo-phenyl hydrazinyl ethyl] benzamide on Mild Steel in Sulphuric Acid Medium |
| title_fullStr | Synthesis, Characterization and Corrosion Protective Efficiency of 2[2-Oxo-phenyl hydrazinyl ethyl] benzamide on Mild Steel in Sulphuric Acid Medium |
| title_full_unstemmed | Synthesis, Characterization and Corrosion Protective Efficiency of 2[2-Oxo-phenyl hydrazinyl ethyl] benzamide on Mild Steel in Sulphuric Acid Medium |
| title_short | Synthesis, Characterization and Corrosion Protective Efficiency of 2[2-Oxo-phenyl hydrazinyl ethyl] benzamide on Mild Steel in Sulphuric Acid Medium |
| title_sort | synthesis characterization and corrosion protective efficiency of 2 2 oxo phenyl hydrazinyl ethyl benzamide on mild steel in sulphuric acid medium |
| url | http://dx.doi.org/10.1155/2010/402878 |
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