Fe⊕-Induced Dehydrogenation of 2-Octyne in the Gas Phase – Evidence for Direct Functionalization of Remote C-H Bonds

Experimental evidence is presented that the Fe⊕-induced dehydrogenation of gaseous 2-octyne cannot be described in terms of the traditional reaction sequence, i.e. oxidative addition of Fe⊕ to a carbon-carbon bond followed by β-hydrogen transfers to the metal centre. Rather, the major reaction path...

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Bibliographic Details
Main Authors: Christian Schulze, Helmut Schwarz
Format: Article
Language:deu
Published: Swiss Chemical Society 1987-02-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9771
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