Mechanochemical Enantiospecific Syntheses of Sulfonimidate Esters and Sulfonimidamides by Various S(VI) Exchange Reactions

Mechanochemical Enantiospecific Syntheses of Sulfonimidate Esters and Sulfonimidamides by Various S(VI) Exchange Reactions

Mechanochemical S(VI) exchange reactions are developed on chiral S(VI)–F and S(VI)–Cl centers that are fast, solvent–free, high–yielding, and enantiospecific. This approach is used to synthesize a range of sulfonimidate esters and sulfonimidamides from sulfonimidoyl fluorides and chlorides under mil...

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Bibliographic Details
Main Authors: Shashank Tripathi, Sidharam P. Pujari, Manoah Romkes, Fedor M. Miloserdov, Hongwei Zhou, Han Zuilhof
Format: Article
Language:English
Published: Wiley-VCH 2025-05-01
Series:ChemistryEurope
Subjects:
chiral click reactions
mechanochemistries
solvent‐free syntheses
SuFEx
sulfur (VI) exchanges
Online Access:https://doi.org/10.1002/ceur.202500006
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https://doi.org/10.1002/ceur.202500006

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