Bis[N,N-bis(diphenylphosphanyl)cyclohexanamine-κ2P,P′]dichloridocobalt(III) tris(μ-diphenylphosphinato-κ2O:O′)bis[chloridocobaltate(II)]–dichloromethane–diethyl ether (1/1.189/0.811)

Bis[N,N-bis(diphenylphosphanyl)cyclohexanamine-κ2P,P′]dichloridocobalt(III) tris(μ-diphenylphosphinato-κ2O:O′)bis[chloridocobaltate(II)]–dichloromethane–diethyl ether (1/1.189/0.811)

The DCM-Et2O solvated title compound, [CoCl2(C30H31NP2)2][Co2(C12H10O2P)3Cl2]·1.189CH2Cl2·0.811C4H10O or [CoCl2{Ph2PN(C6H11)PPh2}2][Co2{Ph2PO2}3Cl2]·1.189DCM·0.811Et2O, is a combination of a cationic CoIII-aminodiphosphine and a dimetallic CoII-diphenylphosphonate anionic species. The asymmetric uni...

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Bibliographic Details
Main Authors: Sizwe J. Zamisa, Adesola A. Adeleke, Dunesha Naicker, Holger B. Friedrich, Bernard Omondi
Format: Article
Language:English
Published: International Union of Crystallography 2025-07-01
Series:IUCrData
Subjects:
crystal structure
co(ii)/co(iii) compound
aminodiphosphine
diphenylphosphonate
Online Access:https://journals.iucr.org/paper?S2414314625006327
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