Carbon monoxide oxidation by oxygen in water-acetonitrile solutions of palladium(II) bromide complexes in the presence of Co(II), Fe(II) and Mn(III) phthalocyaninates

Carbon monoxide oxidation by oxygen in water-acetonitrile solutions of palladium(II) bromide complexes in the presence of Co(II), Fe(II) and Mn(III) phthalocyaninates

Objectives. The objective of this paper was to compare acetylene oxidative dicarbonylation that leads to maleic anhydride with a side reaction of CO oxidation by oxygen in a PdBr2-LiBr-H2C-CH3CN system and in the presence of insoluble (Co) and soluble (Co, Fe, and Mn) phthalocyaninates (PcM).Methods...

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Main Authors: I. V. Oshanina, S. I. Goloborod’ko, E. A. Robinova, I. N. Rusnak, S. A. Nikiforov, S. A. Prokhorov, O. N. Temkin, O. L. Kaliya
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2019-12-01
Series:Тонкие химические технологии
Subjects:
metal complex catalysis
palladium carbonyl complexes
maleic anhydride
carbon monoxide
carbon dioxide
transition metal phthalocyaninates
Online Access:https://www.finechem-mirea.ru/jour/article/view/1575
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https://www.finechem-mirea.ru/jour/article/view/1575

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