Quantum Tunnelling in Triplet Carbenes Explained by Instanton Theory
The temperature-dependent reactivity of three triplet carbenes (denoted as C1, C2 and C3) were investigated using instanton theory. Experiments showed that C1undergoes an intramolecular reaction at very low temperatures, while C2 requires heating, and C3 remains stable despite heating. The reactions...
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| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
2025-04-01
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| Series: | CHIMIA |
| Subjects: | |
| Online Access: | https://www.chimia.ch/chimia/article/view/8978 |
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