Copper Increases the Cooperative Gating of Rat P2X2a Receptor Channels

<b>Background/Objectives:</b> P2X receptor channels are widely expressed in the CNS, where they have multiple functions in health and disease. The rat P2X2a (rP2X2a) receptor channel is modulated by copper, an essential trace element that plays important roles in synaptic modulation and...

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Main Authors: Elias Leiva-Salcedo, Denise Riquelme, Juan Pablo Huidobro-Toro, Claudio Coddou
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Pharmaceuticals
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Online Access:https://www.mdpi.com/1424-8247/17/12/1590
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author Elias Leiva-Salcedo
Denise Riquelme
Juan Pablo Huidobro-Toro
Claudio Coddou
author_facet Elias Leiva-Salcedo
Denise Riquelme
Juan Pablo Huidobro-Toro
Claudio Coddou
author_sort Elias Leiva-Salcedo
collection DOAJ
description <b>Background/Objectives:</b> P2X receptor channels are widely expressed in the CNS, where they have multiple functions in health and disease. The rat P2X2a (rP2X2a) receptor channel is modulated by copper, an essential trace element that plays important roles in synaptic modulation and neurodegenerative disorders. Although essential extracellular amino acids that coordinate copper have been identified, the exact mechanism of copper-induced modulation has not been yet elucidated. <b>Methods</b>: We used HEK293T cells expressing rP2X2a channel(s) and performed outside-out single-channel and whole-cell recordings to explore copper’s effects on rP2X2 currents and determine whether this metal can increase the cooperative gating of rP2X2a channel. <b>Results</b>: In whole-cell recordings and in patches containing 2 or 3 rP2X2a channels, copper enhanced the ATP-induced currents, significantly reducing the ATP EC<sub>50</sub> and increasing the Hill coefficient. Moreover, copper increased the apparent P<sub>o</sub> in patches containing two or three channels. By contrast, in patches containing only one rP2X2a channel, we did not observe any significant changes in ATP EC<sub>50</sub>, the Hill coefficient, or P<sub>o</sub>. <b>Conclusions</b>: Copper modulates the gating of rP2X2a channels, enhancing interchannel cooperativity without altering single-channel conductance or P<sub>o</sub>. This novel regulatory mechanism could be relevant for understanding the role of P2X2 channels in physiological and pathological processes.
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spelling doaj-art-ed6e788264fb434f923985d9b8bb391c2024-12-27T14:45:47ZengMDPI AGPharmaceuticals1424-82472024-11-011712159010.3390/ph17121590Copper Increases the Cooperative Gating of Rat P2X2a Receptor ChannelsElias Leiva-Salcedo0Denise Riquelme1Juan Pablo Huidobro-Toro2Claudio Coddou3Department of Biology, Faculty of Chemistry and Biology, Universidad de Santiago de Chile, Santiago 9170022, ChileDepartment of Biology, Faculty of Chemistry and Biology, Universidad de Santiago de Chile, Santiago 9170022, ChileDepartment of Biology, Faculty of Chemistry and Biology, Universidad de Santiago de Chile, Santiago 9170022, ChileDepartamento de Ciencias Biomédicas, Facultad de Medicina, Universidad Católica del Norte, Coquimbo 1781421, Chile<b>Background/Objectives:</b> P2X receptor channels are widely expressed in the CNS, where they have multiple functions in health and disease. The rat P2X2a (rP2X2a) receptor channel is modulated by copper, an essential trace element that plays important roles in synaptic modulation and neurodegenerative disorders. Although essential extracellular amino acids that coordinate copper have been identified, the exact mechanism of copper-induced modulation has not been yet elucidated. <b>Methods</b>: We used HEK293T cells expressing rP2X2a channel(s) and performed outside-out single-channel and whole-cell recordings to explore copper’s effects on rP2X2 currents and determine whether this metal can increase the cooperative gating of rP2X2a channel. <b>Results</b>: In whole-cell recordings and in patches containing 2 or 3 rP2X2a channels, copper enhanced the ATP-induced currents, significantly reducing the ATP EC<sub>50</sub> and increasing the Hill coefficient. Moreover, copper increased the apparent P<sub>o</sub> in patches containing two or three channels. By contrast, in patches containing only one rP2X2a channel, we did not observe any significant changes in ATP EC<sub>50</sub>, the Hill coefficient, or P<sub>o</sub>. <b>Conclusions</b>: Copper modulates the gating of rP2X2a channels, enhancing interchannel cooperativity without altering single-channel conductance or P<sub>o</sub>. This novel regulatory mechanism could be relevant for understanding the role of P2X2 channels in physiological and pathological processes.https://www.mdpi.com/1424-8247/17/12/1590cooperativityP2X2P2X2asingle channelcoppertrace metals
spellingShingle Elias Leiva-Salcedo
Denise Riquelme
Juan Pablo Huidobro-Toro
Claudio Coddou
Copper Increases the Cooperative Gating of Rat P2X2a Receptor Channels
Pharmaceuticals
cooperativity
P2X2
P2X2a
single channel
copper
trace metals
title Copper Increases the Cooperative Gating of Rat P2X2a Receptor Channels
title_full Copper Increases the Cooperative Gating of Rat P2X2a Receptor Channels
title_fullStr Copper Increases the Cooperative Gating of Rat P2X2a Receptor Channels
title_full_unstemmed Copper Increases the Cooperative Gating of Rat P2X2a Receptor Channels
title_short Copper Increases the Cooperative Gating of Rat P2X2a Receptor Channels
title_sort copper increases the cooperative gating of rat p2x2a receptor channels
topic cooperativity
P2X2
P2X2a
single channel
copper
trace metals
url https://www.mdpi.com/1424-8247/17/12/1590
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AT deniseriquelme copperincreasesthecooperativegatingofratp2x2areceptorchannels
AT juanpablohuidobrotoro copperincreasesthecooperativegatingofratp2x2areceptorchannels
AT claudiocoddou copperincreasesthecooperativegatingofratp2x2areceptorchannels