Internally Catalyzed Hydrogen Atom Transfer (<i>I-CHAT</i>)—A New Class of Reactions in Combustion Chemistry

Internally Catalyzed Hydrogen Atom Transfer (<i>I-CHAT</i>)—A New Class of Reactions in Combustion Chemistry

The current paradigm of low-T combustion and autoignition of hydrocarbons is based on the sequential two-step oxygenation of fuel radicals. The key chain-branching occurs when the second oxygenation adduct (OOQOOH) is isomerized releasing an OH radical and a key <i>ketohydroperoxide</i>...

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Bibliographic Details
Main Authors: Rubik Asatryan, Jason Hudzik, Venus Amiri, Mark T. Swihart
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Molecules
Subjects:
intramolecular catalysis
hydrogen atom transfer
dihydrogen catalysis
autoignition
chain-branching
ketohydroperoxides
Online Access:https://www.mdpi.com/1420-3049/30/3/524
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