Energy Transfer Catalysis Enabled 2,2,2‐Trifluoroethoxy‐Amination of Olefins

Energy Transfer Catalysis Enabled 2,2,2‐Trifluoroethoxy‐Amination of Olefins

A thioxanthone‐catalyzed 2,2,2‐trifluoroethoxyamination of olefins is developed via the formation of the corresponding alkoxy and iminyl radicals using unprecedented, easily prepared, and bench‐stable oxime ethers as bifunctional reagents. To bypass possible side reactions (1,2‐Hydrogen Atom Transfe...

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Bibliographic Details
Main Authors: Floriane Doche, Thibault Gallavardin, Thomas Poisson, Tatiana Besset
Format: Article
Language:English
Published: Wiley-VCH 2025-07-01
Series:ChemistryEurope
Subjects:
alkoxy radical generation
bifunctional reagents
energy transfer
photocatalysis
2,2,2‐trifluoroethoxyamination reactions
Online Access:https://doi.org/10.1002/ceur.202500041
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https://doi.org/10.1002/ceur.202500041

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