Organocatalytic asymmetric synthesis of Tröger’s bases
Abstract The stereochemical course of nitrogen in tertiary amines has long been overlooked because of the low energy barriers for pyramidal inversion between nitrogen-based conformers. Tröger’s base (TB) is a textbook three-dimensional (3D) molecule with N-centered chirality. Despite the major devel...
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| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2025-07-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-025-61772-4 |
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