Intramolekulare Acylgruppenwanderung O-acylierter 1,3-Diketone

At room temperature both Z-isomers of O-acylated 1-acetyl-indan-2-ones are rapidly converted into each other by a thermal intramolecular 1,5-acyl shift. The corresponding E-isomer is thermally stable, a possible O-acyl migration is preceeded by an isomerisation of the C=C double bond, catalysed by...

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Bibliographic Details
Main Authors: Klaus Hartke, Dieter Krampitz, Wolfgang Uhde
Format: Article
Language:deu
Published: Swiss Chemical Society 1973-04-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9079
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