Aqueous photocatalytic oxidation of lignin and humic acids with supported <mml:math> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math>
<p>The photocatalytic oxidation (PCO) of UV-irradiated aqueous solutions containing humic acids and lignin was studied. The photocatalyst <mml:math> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:m...
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Wiley
2006-01-01
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| Series: | International Journal of Photoenergy |
| Online Access: | http://www.hindawi.com/GetArticle.aspx?doi=10.1155/IJP/2006/85927 |
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| description | <p>The photocatalytic oxidation (PCO) of UV-irradiated aqueous solutions containing humic acids and lignin was studied. The photocatalyst <mml:math> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> was attached to buoyant hollow glass microspheres and glass plates. A maximum oxidation efficiency as low as <mml:math> <mml:mn>1.1</mml:mn> </mml:math> and <mml:math> <mml:mn>2.54</mml:mn> </mml:math> mg <mml:math> <mml:msup> <mml:mtext>W</mml:mtext> <mml:mrow> <mml:mo>−</mml:mo><mml:mn>1</mml:mn> </mml:mrow> </mml:msup> </mml:math><mml:math> <mml:msup> <mml:mtext>h</mml:mtext> <mml:mrow> <mml:mo>−</mml:mo><mml:mn>1</mml:mn> </mml:mrow> </mml:msup> </mml:math> for humic acids and lignin, respectively, was achieved in neutral and alkaline media with 25 <mml:math> <mml:msup> <mml:mtext>gm</mml:mtext> <mml:mrow> <mml:mo>−</mml:mo><mml:mn>2</mml:mn> </mml:mrow> </mml:msup> </mml:math> of the buoyant catalyst. In acidic media, efficiency was even lower. The photocatalytic efficiency with the photocatalyst attached to glass plates was about 3 to 4 times higher than that for the buoyant catalyst. Ferrous ions added to acidic solutions did not increase the rate of PCO of humic acids. However the addition of <mml:math> <mml:msup> <mml:mtext>Fe</mml:mtext> <mml:mrow> <mml:mn>2</mml:mn><mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:math> ions, up to 0.05 mM, to the lignin solution leads to a dramatic increase, about 25%, in PCO efficiency. A further increase in ferrous ion concentration results in a decrease in the PCO efficiency of lignin. Proceeding most likely by a radical mechanism, the efficiency of PCO of humic acids did not benefit from an excessive presence of hydroxyl radical promoters, such as hydrogen peroxide, although the reaction rate increased. However, PCO of lignin in the acidic medium, where OH.-radical formation is suppressed, benefited from the introduction of hydrogen peroxide due to promoted radical formation.</p> |
| format | Article |
| id | doaj-art-d9879a3dbaec4f42b5ea7fa2b8ac1b1d |
| institution | Kabale University |
| issn | 1110-662X |
| language | English |
| publishDate | 2006-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Photoenergy |
| spelling | doaj-art-d9879a3dbaec4f42b5ea7fa2b8ac1b1d2025-02-03T01:09:05ZengWileyInternational Journal of Photoenergy1110-662X2006-01-012006Aqueous photocatalytic oxidation of lignin and humic acids with supported <mml:math> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math><p>The photocatalytic oxidation (PCO) of UV-irradiated aqueous solutions containing humic acids and lignin was studied. The photocatalyst <mml:math> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> was attached to buoyant hollow glass microspheres and glass plates. A maximum oxidation efficiency as low as <mml:math> <mml:mn>1.1</mml:mn> </mml:math> and <mml:math> <mml:mn>2.54</mml:mn> </mml:math> mg <mml:math> <mml:msup> <mml:mtext>W</mml:mtext> <mml:mrow> <mml:mo>−</mml:mo><mml:mn>1</mml:mn> </mml:mrow> </mml:msup> </mml:math><mml:math> <mml:msup> <mml:mtext>h</mml:mtext> <mml:mrow> <mml:mo>−</mml:mo><mml:mn>1</mml:mn> </mml:mrow> </mml:msup> </mml:math> for humic acids and lignin, respectively, was achieved in neutral and alkaline media with 25 <mml:math> <mml:msup> <mml:mtext>gm</mml:mtext> <mml:mrow> <mml:mo>−</mml:mo><mml:mn>2</mml:mn> </mml:mrow> </mml:msup> </mml:math> of the buoyant catalyst. In acidic media, efficiency was even lower. The photocatalytic efficiency with the photocatalyst attached to glass plates was about 3 to 4 times higher than that for the buoyant catalyst. Ferrous ions added to acidic solutions did not increase the rate of PCO of humic acids. However the addition of <mml:math> <mml:msup> <mml:mtext>Fe</mml:mtext> <mml:mrow> <mml:mn>2</mml:mn><mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:math> ions, up to 0.05 mM, to the lignin solution leads to a dramatic increase, about 25%, in PCO efficiency. A further increase in ferrous ion concentration results in a decrease in the PCO efficiency of lignin. Proceeding most likely by a radical mechanism, the efficiency of PCO of humic acids did not benefit from an excessive presence of hydroxyl radical promoters, such as hydrogen peroxide, although the reaction rate increased. However, PCO of lignin in the acidic medium, where OH.-radical formation is suppressed, benefited from the introduction of hydrogen peroxide due to promoted radical formation.</p>http://www.hindawi.com/GetArticle.aspx?doi=10.1155/IJP/2006/85927 |
| spellingShingle | Aqueous photocatalytic oxidation of lignin and humic acids with supported <mml:math> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> International Journal of Photoenergy |
| title | Aqueous photocatalytic oxidation of lignin and humic acids with supported <mml:math> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> |
| title_full | Aqueous photocatalytic oxidation of lignin and humic acids with supported <mml:math> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> |
| title_fullStr | Aqueous photocatalytic oxidation of lignin and humic acids with supported <mml:math> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> |
| title_full_unstemmed | Aqueous photocatalytic oxidation of lignin and humic acids with supported <mml:math> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> |
| title_short | Aqueous photocatalytic oxidation of lignin and humic acids with supported <mml:math> <mml:mrow> <mml:msub> <mml:mrow> <mml:mtext>TiO</mml:mtext> </mml:mrow> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> |
| title_sort | aqueous photocatalytic oxidation of lignin and humic acids with supported mml math mml mrow mml msub mml mrow mml mtext tio mml mtext mml mrow mml mn 2 mml mn mml msub mml mrow mml math |
| url | http://www.hindawi.com/GetArticle.aspx?doi=10.1155/IJP/2006/85927 |