ROLE OF Mn(TPP)Cl IN THE EPOXIDATION WITH SINGLET OXYGEN
Mn(TPP)Cl catalyzes cooxidation of olefin in the singlet oxygenation of sulfid. Mn(TPP)Cl is able to transfer an oxygen atom from a peroxidic intermediate generated in singlet oxygenation of sulfide to a metal ion affording metal 0x0 species which is responsible for epoxidation. This system leads to...
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| Format: | Article |
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| Language: | English |
| Published: |
University of Tehran
2000-03-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Online Access: | https://jsciences.ut.ac.ir/article_31301_664b3f878b0da2c921283a01a01e88a5.pdf |
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