Improvement in the Mechanical Properties of High Temperature Shape Memory Alloy (Ti50Ni25Pd25) by Copper Addition
High temperature shape memory alloys Ti50Ni25Pd25 and Ti50Ni20Pd25Cu5 were developed, characterized, and tensile tested in both martensite ( Mf − 50°C) and austenite ( Af + 50°C) phases. The transformation temperatures of ternary Ti50Ni25Pd25 alloy were increased by 11 to 12.5°C by substitution of N...
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Wiley
2015-01-01
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Series: | Advances in Materials Science and Engineering |
Online Access: | http://dx.doi.org/10.1155/2015/434923 |
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author | Saif ur Rehman Mushtaq Khan A. Nusair Khan Syed Husain Imran Jaffery Liaqat Ali Aamir Mubashar |
author_facet | Saif ur Rehman Mushtaq Khan A. Nusair Khan Syed Husain Imran Jaffery Liaqat Ali Aamir Mubashar |
author_sort | Saif ur Rehman |
collection | DOAJ |
description | High temperature shape memory alloys Ti50Ni25Pd25 and Ti50Ni20Pd25Cu5 were developed, characterized, and tensile tested in both martensite ( Mf − 50°C) and austenite ( Af + 50°C) phases. The transformation temperatures of ternary Ti50Ni25Pd25 alloy were increased by 11 to 12.5°C by substitution of Ni with 5 at% Cu. At the same time, transformation heat absorbed and released during forward and reverse martensitic transformation was also increased. In the martensite phase, the mechanical properties, that is, the stress for reorientation of martensite variants and fracture stress, were increased by 33 and 60 MPa, respectively, whereas the fracture strain was decreased by 1.5%. In the austenite phase, the critical stress for slip and fracture stress were increased by 62 and 40.9 MPa, respectively, whereas the fracture strain was decreased by 1.2%. The increase in both stresses was attributed to the solid solution strengthening by substitution of Ni atoms with relatively greater atomic radius of copper (Cu) atoms. The overall results suggest that the addition of 5 at% Cu in place of Ni in Ti50Ni25Pd25 alloy is very beneficial to improving the mechanical and shape memory properties and increasing the transformation temperatures. |
format | Article |
id | doaj-art-d7cbb487cebb493b895b8c68cd7b14e3 |
institution | Kabale University |
issn | 1687-8434 1687-8442 |
language | English |
publishDate | 2015-01-01 |
publisher | Wiley |
record_format | Article |
series | Advances in Materials Science and Engineering |
spelling | doaj-art-d7cbb487cebb493b895b8c68cd7b14e32025-02-03T05:44:03ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422015-01-01201510.1155/2015/434923434923Improvement in the Mechanical Properties of High Temperature Shape Memory Alloy (Ti50Ni25Pd25) by Copper AdditionSaif ur Rehman0Mushtaq Khan1A. Nusair Khan2Syed Husain Imran Jaffery3Liaqat Ali4Aamir Mubashar5School of Mechanical and Manufacturing Engineering (SMME), National University of Science and Technology (NUST), Islamabad 44000, PakistanSchool of Mechanical and Manufacturing Engineering (SMME), National University of Science and Technology (NUST), Islamabad 44000, PakistanInstitute of Industrial Control System, Rawalpindi 46000, PakistanSchool of Mechanical and Manufacturing Engineering (SMME), National University of Science and Technology (NUST), Islamabad 44000, PakistanSchool of Mechanical and Manufacturing Engineering (SMME), National University of Science and Technology (NUST), Islamabad 44000, PakistanSchool of Mechanical and Manufacturing Engineering (SMME), National University of Science and Technology (NUST), Islamabad 44000, PakistanHigh temperature shape memory alloys Ti50Ni25Pd25 and Ti50Ni20Pd25Cu5 were developed, characterized, and tensile tested in both martensite ( Mf − 50°C) and austenite ( Af + 50°C) phases. The transformation temperatures of ternary Ti50Ni25Pd25 alloy were increased by 11 to 12.5°C by substitution of Ni with 5 at% Cu. At the same time, transformation heat absorbed and released during forward and reverse martensitic transformation was also increased. In the martensite phase, the mechanical properties, that is, the stress for reorientation of martensite variants and fracture stress, were increased by 33 and 60 MPa, respectively, whereas the fracture strain was decreased by 1.5%. In the austenite phase, the critical stress for slip and fracture stress were increased by 62 and 40.9 MPa, respectively, whereas the fracture strain was decreased by 1.2%. The increase in both stresses was attributed to the solid solution strengthening by substitution of Ni atoms with relatively greater atomic radius of copper (Cu) atoms. The overall results suggest that the addition of 5 at% Cu in place of Ni in Ti50Ni25Pd25 alloy is very beneficial to improving the mechanical and shape memory properties and increasing the transformation temperatures.http://dx.doi.org/10.1155/2015/434923 |
spellingShingle | Saif ur Rehman Mushtaq Khan A. Nusair Khan Syed Husain Imran Jaffery Liaqat Ali Aamir Mubashar Improvement in the Mechanical Properties of High Temperature Shape Memory Alloy (Ti50Ni25Pd25) by Copper Addition Advances in Materials Science and Engineering |
title | Improvement in the Mechanical Properties of High Temperature Shape Memory Alloy (Ti50Ni25Pd25) by Copper Addition |
title_full | Improvement in the Mechanical Properties of High Temperature Shape Memory Alloy (Ti50Ni25Pd25) by Copper Addition |
title_fullStr | Improvement in the Mechanical Properties of High Temperature Shape Memory Alloy (Ti50Ni25Pd25) by Copper Addition |
title_full_unstemmed | Improvement in the Mechanical Properties of High Temperature Shape Memory Alloy (Ti50Ni25Pd25) by Copper Addition |
title_short | Improvement in the Mechanical Properties of High Temperature Shape Memory Alloy (Ti50Ni25Pd25) by Copper Addition |
title_sort | improvement in the mechanical properties of high temperature shape memory alloy ti50ni25pd25 by copper addition |
url | http://dx.doi.org/10.1155/2015/434923 |
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