Oxidation and Reduction of tert-Butylnitrosoacetylene
Tert-butylnitrosoacetylene [I] can be oxidized to the corresponding nitroacetylene [II] in spite of the low temperature rearrangement of [I] to the isomeric pivaloylcyanide [III]. [I] is reduced with triethylphosphite to an intermediate which reacts with tetramethylethylene formally as the cyanocar...
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| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1975-12-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9261 |
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