Catalytic reduction of benzaldehyde using green synthesized cuprous oxide nanoparticles

Green approach was utilized for the synthesis of Cu2O nanoparticles (NPs) using aqueous leaf extract of Epipremnum aureum and characterized further to understand its particle size, surface morphology, crystallinity, and associated functional groups. XRD pattern of NPs ratified hexagonal crystal stru...

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Main Authors: Samina Ferdousi, Mohammad Saiful Alam, Ershad Ahmmed, Razia Sultana Brishti, Md. Abu Rayhan Khan
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Results in Chemistry
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Online Access:http://www.sciencedirect.com/science/article/pii/S2211715624006313
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author Samina Ferdousi
Mohammad Saiful Alam
Ershad Ahmmed
Razia Sultana Brishti
Md. Abu Rayhan Khan
author_facet Samina Ferdousi
Mohammad Saiful Alam
Ershad Ahmmed
Razia Sultana Brishti
Md. Abu Rayhan Khan
author_sort Samina Ferdousi
collection DOAJ
description Green approach was utilized for the synthesis of Cu2O nanoparticles (NPs) using aqueous leaf extract of Epipremnum aureum and characterized further to understand its particle size, surface morphology, crystallinity, and associated functional groups. XRD pattern of NPs ratified hexagonal crystal structure with average crystallite size to be 56.25 nm, and SEM image divulged porous surface area with grain size to be 70.37 nm. The TEM analysis showed the spherical size of NPs with the average size of 10.87 nm. The thermal stability of Cu2O NPs was observed to be 150 °C. Moreover, the present finding revealed low band gap (2.82 eV) of Cu2O NPs. The synthesized Cu2O NPs were employed for catalytic reduction of benzaldehyde to benzyl alcohol, and significant catalytic efficacy (39 %) was noticed in presence of ethanol. The Cu2O NPs showed significant catalytic activity (34 %) after four cycles along with slight aggregation of NPs possessing the particle size of 103.43 nm.
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institution Kabale University
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publishDate 2025-01-01
publisher Elsevier
record_format Article
series Results in Chemistry
spelling doaj-art-d52175db41274b018df7d89c3e91b0132025-01-29T05:00:37ZengElsevierResults in Chemistry2211-71562025-01-0113101935Catalytic reduction of benzaldehyde using green synthesized cuprous oxide nanoparticlesSamina Ferdousi0Mohammad Saiful Alam1Ershad Ahmmed2Razia Sultana Brishti3Md. Abu Rayhan Khan4Chemistry Discipline, Khulna University, Khulna 9208, BangladeshChemistry Discipline, Khulna University, Khulna 9208, BangladeshForestry & Wood Technology Discipline, Khulna University, Khulna 9208, BangladeshChemistry Discipline, Khulna University, Khulna 9208, Bangladesh; Corresponding authors.Chemistry Discipline, Khulna University, Khulna 9208, Bangladesh; Corresponding authors.Green approach was utilized for the synthesis of Cu2O nanoparticles (NPs) using aqueous leaf extract of Epipremnum aureum and characterized further to understand its particle size, surface morphology, crystallinity, and associated functional groups. XRD pattern of NPs ratified hexagonal crystal structure with average crystallite size to be 56.25 nm, and SEM image divulged porous surface area with grain size to be 70.37 nm. The TEM analysis showed the spherical size of NPs with the average size of 10.87 nm. The thermal stability of Cu2O NPs was observed to be 150 °C. Moreover, the present finding revealed low band gap (2.82 eV) of Cu2O NPs. The synthesized Cu2O NPs were employed for catalytic reduction of benzaldehyde to benzyl alcohol, and significant catalytic efficacy (39 %) was noticed in presence of ethanol. The Cu2O NPs showed significant catalytic activity (34 %) after four cycles along with slight aggregation of NPs possessing the particle size of 103.43 nm.http://www.sciencedirect.com/science/article/pii/S2211715624006313Epipremnum aureumBenzyl alcoholGreen synthesis
spellingShingle Samina Ferdousi
Mohammad Saiful Alam
Ershad Ahmmed
Razia Sultana Brishti
Md. Abu Rayhan Khan
Catalytic reduction of benzaldehyde using green synthesized cuprous oxide nanoparticles
Results in Chemistry
Epipremnum aureum
Benzyl alcohol
Green synthesis
title Catalytic reduction of benzaldehyde using green synthesized cuprous oxide nanoparticles
title_full Catalytic reduction of benzaldehyde using green synthesized cuprous oxide nanoparticles
title_fullStr Catalytic reduction of benzaldehyde using green synthesized cuprous oxide nanoparticles
title_full_unstemmed Catalytic reduction of benzaldehyde using green synthesized cuprous oxide nanoparticles
title_short Catalytic reduction of benzaldehyde using green synthesized cuprous oxide nanoparticles
title_sort catalytic reduction of benzaldehyde using green synthesized cuprous oxide nanoparticles
topic Epipremnum aureum
Benzyl alcohol
Green synthesis
url http://www.sciencedirect.com/science/article/pii/S2211715624006313
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AT ershadahmmed catalyticreductionofbenzaldehydeusinggreensynthesizedcuprousoxidenanoparticles
AT raziasultanabrishti catalyticreductionofbenzaldehydeusinggreensynthesizedcuprousoxidenanoparticles
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