Synthesis, crystal structure and absolute configuration of (3aS,4R,5S,7aR)-7-(but-3-en-1-yn-1-yl)-2,2-dimethyl-3a,4,5,7a-tetrahydro-2H-1,3-benzodioxole-4,5-diol

Synthesis, crystal structure and absolute configuration of (3aS,4R,5S,7aR)-7-(but-3-en-1-yn-1-yl)-2,2-dimethyl-3a,4,5,7a-tetrahydro-2H-1,3-benzodioxole-4,5-diol

The absolute configuration of the title compound, C13H16O4, determined as 1S,2R,3S,4R based on the synthetic pathway, was confirmed by single-crystal X-ray diffraction. The molecule is a relevant intermediary for the synthesis of speciosins, epoxyquinoides or their analogues. The molecule contains f...

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Bibliographic Details
Main Authors: Alejandro Peixoto de Abreu Lima, Enrique Pandolfi, Valeria Schapiro, Leopoldo Suescun
Format: Article
Language:English
Published: International Union of Crystallography 2024-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
speciosins
epoxide opening
chiral bicycle
crystal structure
Online Access:https://journals.iucr.org/paper?S2056989024009733
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