Selective Borylation of C(sp3)−H Bond of Methyl Ethers Catalyzed by Iron Complexes Bearing Anionic Benzene‐Based PCP‐Pincer Ligands

Selective Borylation of C(sp3)−H Bond of Methyl Ethers Catalyzed by Iron Complexes Bearing Anionic Benzene‐Based PCP‐Pincer Ligands

Abstract Highly selective catalytic C(sp3)−H borylation of methoxy groups has been achieved using newly synthesized iron complexes bearing benzene‐based PCP‐type pincer ligands as catalysts. Reactions of various aryl and alkyl methyl ethers as substrates with bis(pinacolato)diboron under mild reacti...

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Bibliographic Details
Main Authors: Shogo Kuriyama, Yuto Suga, Ken Sakata, Yoshiaki Nishibayashi
Format: Article
Language:English
Published: Wiley-VCH 2025-03-01
Series:ChemistryEurope
Subjects:
Boranes
C−H activation
C−H borylation
Iron
Pincer ligand
Online Access:https://doi.org/10.1002/ceur.202400100
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https://doi.org/10.1002/ceur.202400100

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