Supramolecular assembly of covalently modified Anderson-type polyoxometalates and crown ethers towards pseudo-rotaxane structures

Supramolecular assembly of covalently modified Anderson-type polyoxometalates and crown ethers towards pseudo-rotaxane structures

The supramolecular assembly of a series of covalently modified Anderson-type polyoxometalates (POMs) and 18-crown-6 ethers was investigated for the first time. Seven new POM–crown ether complexes were prepared by varying the countercations and the modification mode of the Anderson clusters, and they...

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Bibliographic Details
Main Authors: Yi-An Yin, Wu-Ji Chen, Chun-Yan Liu, Meng-Meng Zhang, Chang-Gen Lin, Haralampos N. Miras, Yu-Fei Song
Format: Article
Language:English
Published: Tsinghua University Press 2025-03-01
Series:Polyoxometalates
Subjects:
polyoxometalate
supramolecular assembly
organic-inorganic hybrid
crown ether
rotaxane
Online Access:https://www.sciopen.com/article/10.26599/POM.2024.9140081
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