Bis[1,2-bis(3,5-dimethylphenyl)ethylene-1,2-dithiolato(1−)]nickel(II)

Bis[1,2-bis(3,5-dimethylphenyl)ethylene-1,2-dithiolato(1−)]nickel(II)

The title compound, [Ni(C18H18S2)2], 1, crystallizes upon an inversion center in monoclinic P21/c with intraligand C—S and C—Cchelate bond lengths that are indicative of the radical monoanionic redox level for the dithiolene ligand. The arene rings are canted at angles of 43.54 (4) and 71.36 (3)° wi...

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Bibliographic Details
Main Authors: Titir Das Gupta, Jackson Guite, LiWen Hirt, Xiaodong Zhang, James P. Donahue
Format: Article
Language:English
Published: International Union of Crystallography 2025-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
dithiolene
nickel
electron-donating
c—h→πarene hydrogen bonds
Online Access:https://journals.iucr.org/paper?S2056989025004293
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