A Comparative Analysis of Laser-Ablated Surface Characteristics Between the Si Face and C Face of Silicon Carbide Substrates

Silicon carbide (SiC) has significant potential as a third-generation semiconductor material due to its exceptional thermal and electronic properties, yet its high hardness and brittleness make processing costly and complex. This study introduces ultraviolet laser ablation as a method for direct SiC...

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Main Authors: Hsin-Yi Tsai, Yu-Hsuan Lin, Kuo-Cheng Huang, J. Andrew Yeh, Yi Yang, Chien-Fang Ding
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Micromachines
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Online Access:https://www.mdpi.com/2072-666X/16/1/62
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author Hsin-Yi Tsai
Yu-Hsuan Lin
Kuo-Cheng Huang
J. Andrew Yeh
Yi Yang
Chien-Fang Ding
author_facet Hsin-Yi Tsai
Yu-Hsuan Lin
Kuo-Cheng Huang
J. Andrew Yeh
Yi Yang
Chien-Fang Ding
author_sort Hsin-Yi Tsai
collection DOAJ
description Silicon carbide (SiC) has significant potential as a third-generation semiconductor material due to its exceptional thermal and electronic properties, yet its high hardness and brittleness make processing costly and complex. This study introduces ultraviolet laser ablation as a method for direct SiC material removal, investigating the effects of varying scanning speeds on surface composition, hardness, and ablation depth. The results indicate optimal processing speeds for the Si and C faces at 200 mm/s and 100 mm/s, respectively. Ablation depth is linearly correlated with laser repetitions, achieving a 25% improvement in removal efficiency at 100 mm/s on the C face compared to higher speeds. A composition analysis shows that the Si and C faces of SiC exhibit consistent ratios of Si, O, and C both before and after ablation. Post-ablation, the proportion of Si and C decreases with an increased presence of oxygen. At scanning speeds below 200 mm/s, the variation in speed has minimal effect on the compositional ratios, indicating a stable elemental distribution across the surface despite differences in processing speed. Hardness testing indicates an initial hardness of 13,896 MPa for the C face, higher than that of the Si face, with both surfaces experiencing a drop to less than 1% of their original hardness (below 50 MPa) after ablation. Lattice structure analysis shows Moissanite-5H SiC and cubic silicon formation on the Si face, while the C face retains partial SiC structure. This study found that when laser parameters are used to process SiC, the processing parameters required on both sides are different and provide important reference information for future industrial processing applications to shorten the time and process cost of SiC surface thinning.
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spelling doaj-art-cdd27f1b162343799f99fd722867ea962025-01-24T13:42:00ZengMDPI AGMicromachines2072-666X2025-01-011616210.3390/mi16010062A Comparative Analysis of Laser-Ablated Surface Characteristics Between the Si Face and C Face of Silicon Carbide SubstratesHsin-Yi Tsai0Yu-Hsuan Lin1Kuo-Cheng Huang2J. Andrew Yeh3Yi Yang4Chien-Fang Ding5Taiwan Instrument Research Institute, National Applied Research Laboratories, Hsinchu 300092, TaiwanTaiwan Instrument Research Institute, National Applied Research Laboratories, Hsinchu 300092, TaiwanTaiwan Instrument Research Institute, National Applied Research Laboratories, Hsinchu 300092, TaiwanDepartment of Power Mechanical Engineering, National Tsing Hua University, Hsinchu 300044, TaiwanDepartment of Biomechatronics Engineering, National Taiwan University, Taipei 106319, TaiwanDepartment of Biomechatronics Engineering, National Taiwan University, Taipei 106319, TaiwanSilicon carbide (SiC) has significant potential as a third-generation semiconductor material due to its exceptional thermal and electronic properties, yet its high hardness and brittleness make processing costly and complex. This study introduces ultraviolet laser ablation as a method for direct SiC material removal, investigating the effects of varying scanning speeds on surface composition, hardness, and ablation depth. The results indicate optimal processing speeds for the Si and C faces at 200 mm/s and 100 mm/s, respectively. Ablation depth is linearly correlated with laser repetitions, achieving a 25% improvement in removal efficiency at 100 mm/s on the C face compared to higher speeds. A composition analysis shows that the Si and C faces of SiC exhibit consistent ratios of Si, O, and C both before and after ablation. Post-ablation, the proportion of Si and C decreases with an increased presence of oxygen. At scanning speeds below 200 mm/s, the variation in speed has minimal effect on the compositional ratios, indicating a stable elemental distribution across the surface despite differences in processing speed. Hardness testing indicates an initial hardness of 13,896 MPa for the C face, higher than that of the Si face, with both surfaces experiencing a drop to less than 1% of their original hardness (below 50 MPa) after ablation. Lattice structure analysis shows Moissanite-5H SiC and cubic silicon formation on the Si face, while the C face retains partial SiC structure. This study found that when laser parameters are used to process SiC, the processing parameters required on both sides are different and provide important reference information for future industrial processing applications to shorten the time and process cost of SiC surface thinning.https://www.mdpi.com/2072-666X/16/1/62silicon carbide (SiC)ultraviolet laserhardnesssurface roughnessoxidation
spellingShingle Hsin-Yi Tsai
Yu-Hsuan Lin
Kuo-Cheng Huang
J. Andrew Yeh
Yi Yang
Chien-Fang Ding
A Comparative Analysis of Laser-Ablated Surface Characteristics Between the Si Face and C Face of Silicon Carbide Substrates
Micromachines
silicon carbide (SiC)
ultraviolet laser
hardness
surface roughness
oxidation
title A Comparative Analysis of Laser-Ablated Surface Characteristics Between the Si Face and C Face of Silicon Carbide Substrates
title_full A Comparative Analysis of Laser-Ablated Surface Characteristics Between the Si Face and C Face of Silicon Carbide Substrates
title_fullStr A Comparative Analysis of Laser-Ablated Surface Characteristics Between the Si Face and C Face of Silicon Carbide Substrates
title_full_unstemmed A Comparative Analysis of Laser-Ablated Surface Characteristics Between the Si Face and C Face of Silicon Carbide Substrates
title_short A Comparative Analysis of Laser-Ablated Surface Characteristics Between the Si Face and C Face of Silicon Carbide Substrates
title_sort comparative analysis of laser ablated surface characteristics between the si face and c face of silicon carbide substrates
topic silicon carbide (SiC)
ultraviolet laser
hardness
surface roughness
oxidation
url https://www.mdpi.com/2072-666X/16/1/62
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