Thermische und säurekatalysierte Umlagerung von N-(α,α-Dimethylallyl)-anilinen
The thermal (t-amyl alcohol, 200 to 250°) and acid catalyzed (2N H2SO4, 50 to 70°) rearrangement of N-(α,α-dimethylallyl)- anilines 1 to yield the corresponding 2-(γ,γ-dimethylallyl)-anilines 2 is described. The kinetic secondary H/D isotope effect for the thermal (kH/kD = 0,83, 237°) as well as fo...
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| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1976-01-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9272 |
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