<i>Meta</i>-Xylene-Based Diamines with Protected Benzyl Sites: Potential NCN Pincer Ligands with Tunable Steric Profiles

<i>Meta</i>-Xylene-Based Diamines with Protected Benzyl Sites: Potential NCN Pincer Ligands with Tunable Steric Profiles

Bulky NCN aryl-diamides featuring methyl groups in the benzyl positions were synthesized with the aim of creating a new class of <i>meta</i>-xylene-based trianionic pincer ligands where the common decomposition pathway of metal pincer complexes via C-H activation is prevented. Sterically...

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Bibliographic Details
Main Authors: Tamina Z. Kirsch, Toren Hynes, Jason D. Masuda, Saurabh S. Chitnis
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Molecules
Subjects:
pincer ligands
coordination chemistry
bismuth
structure
Online Access:https://www.mdpi.com/1420-3049/30/6/1331
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