Alkali Activation of Oil Shale Ash Based Ceramics

Timahdit oil shale was subjected to firing transformation via ceramics processing followed by alkali activation to synthesis a materials combining the mechanical properties of ceramics and Zeolites. The mineralogical transformations during firing oil shale have been studied. The main crystalline pha...

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Main Authors: A. Hamadi, K. Nabih
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/769532
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author A. Hamadi
K. Nabih
author_facet A. Hamadi
K. Nabih
author_sort A. Hamadi
collection DOAJ
description Timahdit oil shale was subjected to firing transformation via ceramics processing followed by alkali activation to synthesis a materials combining the mechanical properties of ceramics and Zeolites. The mineralogical transformations during firing oil shale have been studied. The main crystalline phases found in oil shale ash (OSA) were wollastonite, gehlenite and augite. Modified oil shale ash (MOSA) was obtained with HNO3 acid-leaching in the aim to diminish Ca content. Our experimental approach required a NaOH alkaline activating solution with different concentrations (0.5; 1; 2; 4; 6 and 8M). In our study, X-ray diffraction (XDR), Fourier transform infrared (FTIR) and SEM/EDS analysis were used to evaluate the effect of alkali activation on the structural arrangement of the starting materials (OSA and MOSA) in our study. The quantity and the type of the produced zeolites depended critically on the starting materials and on the NaOH concentration.
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institution Kabale University
issn 0973-4945
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publishDate 2012-01-01
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spelling doaj-art-b3afbca377f54bb981a90ef40bfbb4442025-02-03T06:01:50ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01931373138810.1155/2012/769532Alkali Activation of Oil Shale Ash Based CeramicsA. Hamadi0K. Nabih1Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Département de Chimie Avenue Ibn Batouta, B.P. 1014 Rabat, MoroccoLaboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Département de Chimie Avenue Ibn Batouta, B.P. 1014 Rabat, MoroccoTimahdit oil shale was subjected to firing transformation via ceramics processing followed by alkali activation to synthesis a materials combining the mechanical properties of ceramics and Zeolites. The mineralogical transformations during firing oil shale have been studied. The main crystalline phases found in oil shale ash (OSA) were wollastonite, gehlenite and augite. Modified oil shale ash (MOSA) was obtained with HNO3 acid-leaching in the aim to diminish Ca content. Our experimental approach required a NaOH alkaline activating solution with different concentrations (0.5; 1; 2; 4; 6 and 8M). In our study, X-ray diffraction (XDR), Fourier transform infrared (FTIR) and SEM/EDS analysis were used to evaluate the effect of alkali activation on the structural arrangement of the starting materials (OSA and MOSA) in our study. The quantity and the type of the produced zeolites depended critically on the starting materials and on the NaOH concentration.http://dx.doi.org/10.1155/2012/769532
spellingShingle A. Hamadi
K. Nabih
Alkali Activation of Oil Shale Ash Based Ceramics
E-Journal of Chemistry
title Alkali Activation of Oil Shale Ash Based Ceramics
title_full Alkali Activation of Oil Shale Ash Based Ceramics
title_fullStr Alkali Activation of Oil Shale Ash Based Ceramics
title_full_unstemmed Alkali Activation of Oil Shale Ash Based Ceramics
title_short Alkali Activation of Oil Shale Ash Based Ceramics
title_sort alkali activation of oil shale ash based ceramics
url http://dx.doi.org/10.1155/2012/769532
work_keys_str_mv AT ahamadi alkaliactivationofoilshaleashbasedceramics
AT knabih alkaliactivationofoilshaleashbasedceramics