Reactivity of Imidazole‐ and Pyridine‐Carboxaldehydes for Gem‐Diol and Hemiacetal Generation: Theoretical and Experimental Insights
Abstract Gem‐diols are defined as organic molecules carrying two hydroxyl groups at the same carbon atom, which is the result of the nucleophilic addition of water to a carbonyl group. In this work, the generation of the hydrated or hemiacetal forms using pyridine‐ and imidazole‐carboxaldehyde isome...
Saved in:
| Main Authors: | Ayelén F. Crespi, Emiliano Barrionuevo, Gabriel Jasinski, Albertina G. Moglioni, Daniel Vega, Juan M. Lázaro‐Martínez |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH
2025-08-01
|
| Series: | ChemistryOpen |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/open.202400411 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Similar Items
-
A Simple NMR‐Based Rule for Stereochemical Assignment of 1,5‐Diols in Polyketides
by: Max Deering, et al.
Published: (2025-05-01) -
Bioconversion of Alpha-Cembratriene-4,6-diol into High-Value Compound Farnesal Through Employment of a Novel <i>Stenotrophomonas maltophilia</i> H3-1 Strain
by: Shen Huang, et al.
Published: (2025-02-01) -
Solvatochromic Parameters of Four Amines in Propane-1,3-diol at 298.15 K
by: Maria-Luísa C. J. Moita, et al.
Published: (2025-03-01) -
Introducing mGems, mBio’s new review type
by: Marcio L. Rodrigues, et al.
Published: (2025-03-01) -
Synthesis of 2,2,5-Trisubstituted Tetrahydrofurans by Ferrocenium-Catalyzed Dehydrative Diol Cyclization Reactions
by: Cody D. Amann, et al.
Published: (2025-02-01)