Reactivity of Imidazole‐ and Pyridine‐Carboxaldehydes for Gem‐Diol and Hemiacetal Generation: Theoretical and Experimental Insights

Reactivity of Imidazole‐ and Pyridine‐Carboxaldehydes for Gem‐Diol and Hemiacetal Generation: Theoretical and Experimental Insights

Abstract Gem‐diols are defined as organic molecules carrying two hydroxyl groups at the same carbon atom, which is the result of the nucleophilic addition of water to a carbonyl group. In this work, the generation of the hydrated or hemiacetal forms using pyridine‐ and imidazole‐carboxaldehyde isome...

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Bibliographic Details
Main Authors: Ayelén F. Crespi, Emiliano Barrionuevo, Gabriel Jasinski, Albertina G. Moglioni, Daniel Vega, Juan M. Lázaro‐Martínez
Format: Article
Language:English
Published: Wiley-VCH 2025-08-01
Series:ChemistryOpen
Subjects:
Pyridinecarboxaldehydes
Imidazolecarboxaldehydes
NMR
Gem-diol
Theoretical calculations
Online Access:https://doi.org/10.1002/open.202400411
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https://doi.org/10.1002/open.202400411

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