Metal-Free Synthesis of Benzimidazolinones via Oxidative Cyclization Under Hypervalent Iodine Catalysis

Metal-Free Synthesis of Benzimidazolinones via Oxidative Cyclization Under Hypervalent Iodine Catalysis

Benzimidazolinones exhibit unique biological activities and serve as building blocks in synthesizing pharmaceutical compounds. Although multiple synthetic approaches involving intermolecular cyclization reactions have been reported, intramolecular cyclization reactions are scarce, and more rational...

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Bibliographic Details
Main Authors: Mayu Hirashima, Syotaro Hamatani, Hirotaka Sasa, Naoko Takenaga, Tomonori Hanasaki, Toshifumi Dohi
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Chemistry
Subjects:
hypervalent iodine catalysis
oxidative cyclization
electrophilic amination
benzimidazolinone
<i>N</i>-methoxy-<i>N</i>′-phenylurea
Online Access:https://www.mdpi.com/2624-8549/7/2/50
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