Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy
Surface tension and Raman spectra containing hydrogen bonding in acetonitrile aqueous solutions with different mole ratios were obtained. Varied surface tension and hydrogen bonding in the mixed solution were discussed. For this purpose, the OH stretching bands were fitted into three Gaussian compon...
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Format: | Article |
Language: | English |
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Wiley
2019-01-01
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Series: | International Journal of Analytical Chemistry |
Online Access: | http://dx.doi.org/10.1155/2019/7975237 |
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author | Nannan Wu Shunli Ouyang Junjie Cui Shiliang Liu Mingzhe Zhang Qingcheng Hu Baokun Huang |
author_facet | Nannan Wu Shunli Ouyang Junjie Cui Shiliang Liu Mingzhe Zhang Qingcheng Hu Baokun Huang |
author_sort | Nannan Wu |
collection | DOAJ |
description | Surface tension and Raman spectra containing hydrogen bonding in acetonitrile aqueous solutions with different mole ratios were obtained. Varied surface tension and hydrogen bonding in the mixed solution were discussed. For this purpose, the OH stretching bands were fitted into three Gaussian components to which different hydrogen-bonded water samples were assigned. Furthermore, the microstructures of binary solution were analyzed. The results indicated that the surface tension decreases dramatically with the enhancement of hydrogen bonds in the mixture. A spectroscopic method for studying the macroscopic properties of aqueous solutions was employed. The direct experiment results provided the relationship between surface tension and microstructure in aqueous solutions. |
format | Article |
id | doaj-art-a645f11fb1a14ffba35c0cafa7ecc614 |
institution | Kabale University |
issn | 1687-8760 1687-8779 |
language | English |
publishDate | 2019-01-01 |
publisher | Wiley |
record_format | Article |
series | International Journal of Analytical Chemistry |
spelling | doaj-art-a645f11fb1a14ffba35c0cafa7ecc6142025-02-03T01:07:16ZengWileyInternational Journal of Analytical Chemistry1687-87601687-87792019-01-01201910.1155/2019/79752377975237Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman SpectroscopyNannan Wu0Shunli Ouyang1Junjie Cui2Shiliang Liu3Mingzhe Zhang4Qingcheng Hu5Baokun Huang6Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaKey Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaKey Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaSchool of Energy and Environment, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaKey Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaKey Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaElectronic Engineering School, Huaihai Institute of Technology, Lianyungang 222000, ChinaSurface tension and Raman spectra containing hydrogen bonding in acetonitrile aqueous solutions with different mole ratios were obtained. Varied surface tension and hydrogen bonding in the mixed solution were discussed. For this purpose, the OH stretching bands were fitted into three Gaussian components to which different hydrogen-bonded water samples were assigned. Furthermore, the microstructures of binary solution were analyzed. The results indicated that the surface tension decreases dramatically with the enhancement of hydrogen bonds in the mixture. A spectroscopic method for studying the macroscopic properties of aqueous solutions was employed. The direct experiment results provided the relationship between surface tension and microstructure in aqueous solutions.http://dx.doi.org/10.1155/2019/7975237 |
spellingShingle | Nannan Wu Shunli Ouyang Junjie Cui Shiliang Liu Mingzhe Zhang Qingcheng Hu Baokun Huang Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy International Journal of Analytical Chemistry |
title | Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy |
title_full | Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy |
title_fullStr | Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy |
title_full_unstemmed | Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy |
title_short | Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy |
title_sort | investigation on the influence of microstructure based on hydrogen bonding on surface tension by raman spectroscopy |
url | http://dx.doi.org/10.1155/2019/7975237 |
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