Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy

Surface tension and Raman spectra containing hydrogen bonding in acetonitrile aqueous solutions with different mole ratios were obtained. Varied surface tension and hydrogen bonding in the mixed solution were discussed. For this purpose, the OH stretching bands were fitted into three Gaussian compon...

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Main Authors: Nannan Wu, Shunli Ouyang, Junjie Cui, Shiliang Liu, Mingzhe Zhang, Qingcheng Hu, Baokun Huang
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:International Journal of Analytical Chemistry
Online Access:http://dx.doi.org/10.1155/2019/7975237
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author Nannan Wu
Shunli Ouyang
Junjie Cui
Shiliang Liu
Mingzhe Zhang
Qingcheng Hu
Baokun Huang
author_facet Nannan Wu
Shunli Ouyang
Junjie Cui
Shiliang Liu
Mingzhe Zhang
Qingcheng Hu
Baokun Huang
author_sort Nannan Wu
collection DOAJ
description Surface tension and Raman spectra containing hydrogen bonding in acetonitrile aqueous solutions with different mole ratios were obtained. Varied surface tension and hydrogen bonding in the mixed solution were discussed. For this purpose, the OH stretching bands were fitted into three Gaussian components to which different hydrogen-bonded water samples were assigned. Furthermore, the microstructures of binary solution were analyzed. The results indicated that the surface tension decreases dramatically with the enhancement of hydrogen bonds in the mixture. A spectroscopic method for studying the macroscopic properties of aqueous solutions was employed. The direct experiment results provided the relationship between surface tension and microstructure in aqueous solutions.
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institution Kabale University
issn 1687-8760
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language English
publishDate 2019-01-01
publisher Wiley
record_format Article
series International Journal of Analytical Chemistry
spelling doaj-art-a645f11fb1a14ffba35c0cafa7ecc6142025-02-03T01:07:16ZengWileyInternational Journal of Analytical Chemistry1687-87601687-87792019-01-01201910.1155/2019/79752377975237Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman SpectroscopyNannan Wu0Shunli Ouyang1Junjie Cui2Shiliang Liu3Mingzhe Zhang4Qingcheng Hu5Baokun Huang6Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaKey Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaKey Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaSchool of Energy and Environment, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaKey Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaKey Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, ChinaElectronic Engineering School, Huaihai Institute of Technology, Lianyungang 222000, ChinaSurface tension and Raman spectra containing hydrogen bonding in acetonitrile aqueous solutions with different mole ratios were obtained. Varied surface tension and hydrogen bonding in the mixed solution were discussed. For this purpose, the OH stretching bands were fitted into three Gaussian components to which different hydrogen-bonded water samples were assigned. Furthermore, the microstructures of binary solution were analyzed. The results indicated that the surface tension decreases dramatically with the enhancement of hydrogen bonds in the mixture. A spectroscopic method for studying the macroscopic properties of aqueous solutions was employed. The direct experiment results provided the relationship between surface tension and microstructure in aqueous solutions.http://dx.doi.org/10.1155/2019/7975237
spellingShingle Nannan Wu
Shunli Ouyang
Junjie Cui
Shiliang Liu
Mingzhe Zhang
Qingcheng Hu
Baokun Huang
Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy
International Journal of Analytical Chemistry
title Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy
title_full Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy
title_fullStr Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy
title_full_unstemmed Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy
title_short Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy
title_sort investigation on the influence of microstructure based on hydrogen bonding on surface tension by raman spectroscopy
url http://dx.doi.org/10.1155/2019/7975237
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