High-temperature electrochemical synthesis of carbon-containing inorganic compounds under excessive carbon dioxide pressure
Features of the electroreduction of carbon dioxide dissolved in the equimolar melt of sodium and potassium chlorides under excessive pressure of up to 1.7 MPa have been studied by cyclic voltametry over a wide polarization rate range. It has been found that the electrode process occurs in two stages...
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| Format: | Article |
| Language: | English |
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University of Belgrade, Technical Faculty, Bor
2003-01-01
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| Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302281N.pdf |
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| author | Novoselova I.A. Volkov S.V. Oliinyk N.F. Shapoval V.I. |
| author_facet | Novoselova I.A. Volkov S.V. Oliinyk N.F. Shapoval V.I. |
| author_sort | Novoselova I.A. |
| collection | DOAJ |
| description | Features of the electroreduction of carbon dioxide dissolved in the equimolar melt of sodium and potassium chlorides under excessive pressure of up to 1.7 MPa have been studied by cyclic voltametry over a wide polarization rate range. It has been found that the electrode process occurs in two stages at sweep rates of ≤0.1 V s-1, and its mechanism has been suggested. The cathodic product is polycrystalline graphite. Systems and conditions for producing two- and three-component refractory metal carbides using CO2 as a synthesis component have been selected. |
| format | Article |
| id | doaj-art-a18fad60e9df40d39224ad4e30795295 |
| institution | Kabale University |
| issn | 1450-5339 |
| language | English |
| publishDate | 2003-01-01 |
| publisher | University of Belgrade, Technical Faculty, Bor |
| record_format | Article |
| series | Journal of Mining and Metallurgy. Section B: Metallurgy |
| spelling | doaj-art-a18fad60e9df40d39224ad4e307952952025-02-02T03:41:46ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392003-01-01391-228129310.2298/JMMB0302281NHigh-temperature electrochemical synthesis of carbon-containing inorganic compounds under excessive carbon dioxide pressureNovoselova I.A.Volkov S.V.Oliinyk N.F.Shapoval V.I.Features of the electroreduction of carbon dioxide dissolved in the equimolar melt of sodium and potassium chlorides under excessive pressure of up to 1.7 MPa have been studied by cyclic voltametry over a wide polarization rate range. It has been found that the electrode process occurs in two stages at sweep rates of ≤0.1 V s-1, and its mechanism has been suggested. The cathodic product is polycrystalline graphite. Systems and conditions for producing two- and three-component refractory metal carbides using CO2 as a synthesis component have been selected.http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302281N.pdfelectrochemical synthesisvoltammetrycarbon dioxidecarbon filmsrefractorycarbides |
| spellingShingle | Novoselova I.A. Volkov S.V. Oliinyk N.F. Shapoval V.I. High-temperature electrochemical synthesis of carbon-containing inorganic compounds under excessive carbon dioxide pressure Journal of Mining and Metallurgy. Section B: Metallurgy electrochemical synthesis voltammetry carbon dioxide carbon films refractorycarbides |
| title | High-temperature electrochemical synthesis of carbon-containing inorganic compounds under excessive carbon dioxide pressure |
| title_full | High-temperature electrochemical synthesis of carbon-containing inorganic compounds under excessive carbon dioxide pressure |
| title_fullStr | High-temperature electrochemical synthesis of carbon-containing inorganic compounds under excessive carbon dioxide pressure |
| title_full_unstemmed | High-temperature electrochemical synthesis of carbon-containing inorganic compounds under excessive carbon dioxide pressure |
| title_short | High-temperature electrochemical synthesis of carbon-containing inorganic compounds under excessive carbon dioxide pressure |
| title_sort | high temperature electrochemical synthesis of carbon containing inorganic compounds under excessive carbon dioxide pressure |
| topic | electrochemical synthesis voltammetry carbon dioxide carbon films refractorycarbides |
| url | http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302281N.pdf |
| work_keys_str_mv | AT novoselovaia hightemperatureelectrochemicalsynthesisofcarboncontaininginorganiccompoundsunderexcessivecarbondioxidepressure AT volkovsv hightemperatureelectrochemicalsynthesisofcarboncontaininginorganiccompoundsunderexcessivecarbondioxidepressure AT oliinyknf hightemperatureelectrochemicalsynthesisofcarboncontaininginorganiccompoundsunderexcessivecarbondioxidepressure AT shapovalvi hightemperatureelectrochemicalsynthesisofcarboncontaininginorganiccompoundsunderexcessivecarbondioxidepressure |