Ligand‐Dependent Chemoselectivity in Gold‐Catalyzed Reactions between Anthranils and Diynamides. Formation of Spiro Azacyclic Compounds versus 1‐Imino‐1H‐Indene‐3‐Carboximidamides
Gold‐catalyzed reactions between anthranils and diynamides have been investigated, and their reaction chemoselectivity relies on the types of gold catalysts. With the same anthranil/diynamide mixtures, the use of PPh3AuCl/AgNTf2 leads to formation of spiro azacyclic compounds, whereas P(t‐Bu)2(o‐bip...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH
2025-07-01
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| Series: | ChemistryEurope |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/ceur.202500068 |
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