Polarity dependent predictable and random resistive switching in forming-free unipolar memristors

Polycrystalline, hexagonal HoMnO3 thin films sandwiched between an un-patterned Pt/Ti bottom electrode and a circularly patterned Al top electrode reveal forming-free, polarity dependent predictable and random, unipolar resistive switching with stable retention, and a resistance ratio between high r...

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Main Authors: Venkata Rao Rayapati, Sahitya Varma Vegesna, Vinayak Jayram Bhat, Daniel Blaschke, Marco Diegel, Andrea Dellith, Jan Dellith, Danilo Bürger, Ilona Skorupa, Heidemarie Schmidt
Format: Article
Language:English
Published: AIP Publishing LLC 2025-01-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/5.0226262
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author Venkata Rao Rayapati
Sahitya Varma Vegesna
Vinayak Jayram Bhat
Daniel Blaschke
Marco Diegel
Andrea Dellith
Jan Dellith
Danilo Bürger
Ilona Skorupa
Heidemarie Schmidt
author_facet Venkata Rao Rayapati
Sahitya Varma Vegesna
Vinayak Jayram Bhat
Daniel Blaschke
Marco Diegel
Andrea Dellith
Jan Dellith
Danilo Bürger
Ilona Skorupa
Heidemarie Schmidt
author_sort Venkata Rao Rayapati
collection DOAJ
description Polycrystalline, hexagonal HoMnO3 thin films sandwiched between an un-patterned Pt/Ti bottom electrode and a circularly patterned Al top electrode reveal forming-free, polarity dependent predictable and random, unipolar resistive switching with stable retention, and a resistance ratio between high resistance state (HRS) and low resistance state (LRS) larger than 104. An equivalent circuit model is proposed to describe the HoMnO3 memristor as a three-layered capacitor structure. Based on the energy band diagram of the HoMnO3 structure under applied negative and positive write bias, polarity dependent, predictable, and random resistive switching is explained. Furthermore, the conductance in LRS until RESET and in HRS until SET has been investigated. The conductance in LRS is large and constant until RESET bias is reached. The conductance in HRS increases from nearly zero to quantum conductance G0 (2e2/h) until SET bias is reached.
format Article
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institution Kabale University
issn 2158-3226
language English
publishDate 2025-01-01
publisher AIP Publishing LLC
record_format Article
series AIP Advances
spelling doaj-art-9b8bcdf5c218431fadec4899de85e6342025-02-03T16:40:43ZengAIP Publishing LLCAIP Advances2158-32262025-01-01151015313015313-1110.1063/5.0226262Polarity dependent predictable and random resistive switching in forming-free unipolar memristorsVenkata Rao Rayapati0Sahitya Varma Vegesna1Vinayak Jayram Bhat2Daniel Blaschke3Marco Diegel4Andrea Dellith5Jan Dellith6Danilo Bürger7Ilona Skorupa8Heidemarie Schmidt9Leibniz Institute of Photonic Technology, Albert-Einstein-Straße 9, 07745 Jena, GermanyLeibniz Institute of Photonic Technology, Albert-Einstein-Straße 9, 07745 Jena, GermanyLeibniz Institute of Photonic Technology, Albert-Einstein-Straße 9, 07745 Jena, GermanyLeibniz Institute of Photonic Technology, Albert-Einstein-Straße 9, 07745 Jena, GermanyLeibniz Institute of Photonic Technology, Albert-Einstein-Straße 9, 07745 Jena, GermanyLeibniz Institute of Photonic Technology, Albert-Einstein-Straße 9, 07745 Jena, GermanyLeibniz Institute of Photonic Technology, Albert-Einstein-Straße 9, 07745 Jena, GermanyInstitute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf e.V., 01328 Dresden, GermanyInstitute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf e.V., 01328 Dresden, GermanyLeibniz Institute of Photonic Technology, Albert-Einstein-Straße 9, 07745 Jena, GermanyPolycrystalline, hexagonal HoMnO3 thin films sandwiched between an un-patterned Pt/Ti bottom electrode and a circularly patterned Al top electrode reveal forming-free, polarity dependent predictable and random, unipolar resistive switching with stable retention, and a resistance ratio between high resistance state (HRS) and low resistance state (LRS) larger than 104. An equivalent circuit model is proposed to describe the HoMnO3 memristor as a three-layered capacitor structure. Based on the energy band diagram of the HoMnO3 structure under applied negative and positive write bias, polarity dependent, predictable, and random resistive switching is explained. Furthermore, the conductance in LRS until RESET and in HRS until SET has been investigated. The conductance in LRS is large and constant until RESET bias is reached. The conductance in HRS increases from nearly zero to quantum conductance G0 (2e2/h) until SET bias is reached.http://dx.doi.org/10.1063/5.0226262
spellingShingle Venkata Rao Rayapati
Sahitya Varma Vegesna
Vinayak Jayram Bhat
Daniel Blaschke
Marco Diegel
Andrea Dellith
Jan Dellith
Danilo Bürger
Ilona Skorupa
Heidemarie Schmidt
Polarity dependent predictable and random resistive switching in forming-free unipolar memristors
AIP Advances
title Polarity dependent predictable and random resistive switching in forming-free unipolar memristors
title_full Polarity dependent predictable and random resistive switching in forming-free unipolar memristors
title_fullStr Polarity dependent predictable and random resistive switching in forming-free unipolar memristors
title_full_unstemmed Polarity dependent predictable and random resistive switching in forming-free unipolar memristors
title_short Polarity dependent predictable and random resistive switching in forming-free unipolar memristors
title_sort polarity dependent predictable and random resistive switching in forming free unipolar memristors
url http://dx.doi.org/10.1063/5.0226262
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