Ligand-controlled divergent asymmetric C(sp3)−H and C(sp3)−O insertion via vinyl cations

Abstract The insertion of either C−H bond or C−O bond via bond cleavage has proven to be a very attractive strategy for the construction of C−C and C−O bonds in organic synthesis. However, such divergent catalytic asymmetric reactions for the selective formation of C(sp3)−H insertion and formal C(sp...

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Bibliographic Details
Main Authors: Cui-Ting Li, Li-Gao Liu, Jia-Zheng Li, Hao-Xuan Dong, Roman A. Novikov, Ze-Shu Wang, Xin Hong, Bo Zhou, Long-Wu Ye
Format: Article
Language:English
Published: Nature Portfolio 2025-05-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-59328-7
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