Synthesis and Characterization of Metal Particles Using Malic Acid-Derived Polyamides, Polyhydrazides, and Hydrazides
Malic acid-derived polyamides, polyhydrazides, and hydrazides exhibit strong potential for a variety of biological applications. This study demonstrates the synthesis of cobalt, silver, copper, zinc, and iron particles by a facile chemical reduction approach utilizing malic acid-derived polyamides,...
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| Format: | Article |
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2024-12-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/30/1/134 |
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| author | Muhammad Farhan Qadir Somavia Ameen Rida Fatima Nadim Ullah Gamal A. Shazly Abu Summama Sadavi Bilal Mehwish Nazar Anoosha Sajjad Tawaf Ali Shah Yukun Yang |
| author_facet | Muhammad Farhan Qadir Somavia Ameen Rida Fatima Nadim Ullah Gamal A. Shazly Abu Summama Sadavi Bilal Mehwish Nazar Anoosha Sajjad Tawaf Ali Shah Yukun Yang |
| author_sort | Muhammad Farhan Qadir |
| collection | DOAJ |
| description | Malic acid-derived polyamides, polyhydrazides, and hydrazides exhibit strong potential for a variety of biological applications. This study demonstrates the synthesis of cobalt, silver, copper, zinc, and iron particles by a facile chemical reduction approach utilizing malic acid-derived polyamides, polyhydrazides, and hydrazides as stabilizing and reducing agents. Comprehensive characterization of the particles was performed using UV–Vis spectroscopy, FTIR, XRD, SEM, and EDX analysis. The synthesized particles included both zero-valent metals and oxides exhibiting mixed-phase compositions that may influence their functional properties. UV–vis analysis confirmed the formation of particles represented by the surface plasmon resonance (SPR) peaks specific to each metal particle. FTIR spectroscopy revealed the interaction of the metal particles with the polymer matrix owing to the significant contribution of functional groups in the processes of reduction and stabilization. Further structural insights were obtained via X-ray diffraction (XRD), which identified crystalline phases, and scanning electron microscopy (SEM), which demonstrated uniform morphologies. Additionally, energy-dispersive X-ray (EDX) analysis provided compositional details, affirming the purity and distribution of metallic elements. These findings highlight the potential of malic acid-derived polymers as versatile agents for nanoparticle synthesis with applications in catalysis, sensing, and biomedical technologies. |
| format | Article |
| id | doaj-art-93e9e7bde03f43a2b04b29f0191adddb |
| institution | Kabale University |
| issn | 1420-3049 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj-art-93e9e7bde03f43a2b04b29f0191adddb2025-01-10T13:18:59ZengMDPI AGMolecules1420-30492024-12-0130113410.3390/molecules30010134Synthesis and Characterization of Metal Particles Using Malic Acid-Derived Polyamides, Polyhydrazides, and HydrazidesMuhammad Farhan Qadir0Somavia Ameen1Rida Fatima2Nadim Ullah3Gamal A. Shazly4Abu Summama Sadavi Bilal5Mehwish Nazar6Anoosha Sajjad7Tawaf Ali Shah8Yukun Yang9School of Life Science, Shanxi University, Taiyuan 030006, ChinaDepartment of Chemistry, School of Science, Tianjin Key Laboratory of Molecular Optoelectronic Science, Tianjin University, Tianjin 300072, ChinaInstitute of Chemical Sciences, Bahauddin Zakariya University, Multan 60000, PakistanInstitute of Chemical Sciences, University of Peshawar, Peshawar 25120, PakistanDepartment of Pharmaceutics, College of Pharmacy, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Mechanical Engineering, University of Engineering and Technology, Taxila 47080, PakistanDepartment of Chemistry, School of Science, University of Management and Technology, Lahore 42000, PakistanChemistry Department, Islamia College University, Peshawar 25000, PakistanCollege of Agriculture Engineering and Food Sciences, Shandong University of Technology, Zibo 255000, ChinaSchool of Life Science, Shanxi University, Taiyuan 030006, ChinaMalic acid-derived polyamides, polyhydrazides, and hydrazides exhibit strong potential for a variety of biological applications. This study demonstrates the synthesis of cobalt, silver, copper, zinc, and iron particles by a facile chemical reduction approach utilizing malic acid-derived polyamides, polyhydrazides, and hydrazides as stabilizing and reducing agents. Comprehensive characterization of the particles was performed using UV–Vis spectroscopy, FTIR, XRD, SEM, and EDX analysis. The synthesized particles included both zero-valent metals and oxides exhibiting mixed-phase compositions that may influence their functional properties. UV–vis analysis confirmed the formation of particles represented by the surface plasmon resonance (SPR) peaks specific to each metal particle. FTIR spectroscopy revealed the interaction of the metal particles with the polymer matrix owing to the significant contribution of functional groups in the processes of reduction and stabilization. Further structural insights were obtained via X-ray diffraction (XRD), which identified crystalline phases, and scanning electron microscopy (SEM), which demonstrated uniform morphologies. Additionally, energy-dispersive X-ray (EDX) analysis provided compositional details, affirming the purity and distribution of metallic elements. These findings highlight the potential of malic acid-derived polymers as versatile agents for nanoparticle synthesis with applications in catalysis, sensing, and biomedical technologies.https://www.mdpi.com/1420-3049/30/1/134metal particlespolyamidepolyhydrazidehydrazide |
| spellingShingle | Muhammad Farhan Qadir Somavia Ameen Rida Fatima Nadim Ullah Gamal A. Shazly Abu Summama Sadavi Bilal Mehwish Nazar Anoosha Sajjad Tawaf Ali Shah Yukun Yang Synthesis and Characterization of Metal Particles Using Malic Acid-Derived Polyamides, Polyhydrazides, and Hydrazides Molecules metal particles polyamide polyhydrazide hydrazide |
| title | Synthesis and Characterization of Metal Particles Using Malic Acid-Derived Polyamides, Polyhydrazides, and Hydrazides |
| title_full | Synthesis and Characterization of Metal Particles Using Malic Acid-Derived Polyamides, Polyhydrazides, and Hydrazides |
| title_fullStr | Synthesis and Characterization of Metal Particles Using Malic Acid-Derived Polyamides, Polyhydrazides, and Hydrazides |
| title_full_unstemmed | Synthesis and Characterization of Metal Particles Using Malic Acid-Derived Polyamides, Polyhydrazides, and Hydrazides |
| title_short | Synthesis and Characterization of Metal Particles Using Malic Acid-Derived Polyamides, Polyhydrazides, and Hydrazides |
| title_sort | synthesis and characterization of metal particles using malic acid derived polyamides polyhydrazides and hydrazides |
| topic | metal particles polyamide polyhydrazide hydrazide |
| url | https://www.mdpi.com/1420-3049/30/1/134 |
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