Der Mechanismus der Umlagerung substituierter Aminoacrylderivate

Thioacetic acid and dithioacetic acid react with push-pull- acetylenes of the type (CH3)2N—C=C—CO-R (1) in the same way as other carboxylic acids: The addition to dimethylaminopropinal (1a) at low temperatures yields, after rearrangement of the very instable primary adducts, Z-3-acetoxy-N,N-di- met...

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Bibliographic Details
Main Authors: M. Neuenschwander, G. Bart, A. Niederhauser
Format: Article
Language:deu
Published: Swiss Chemical Society 1973-02-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9062
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