A non-metal-to-metal I+−Ag+ coordination bond

Abstract Metal-metal bonds between metal cations are ubiquitous in coordination complexes, whereas similar bonding characteristics between non-metal and metal cations are not. Here, we report an X-ray crystal structure of a centrosymmetric complex [Ag(m-O3SCF3)2{(4MePyNO)2I}]2 (1-AgI), where the iod...

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Bibliographic Details
Main Authors: Rakesh Puttreddy, Niklas Limberg, Carsten Müller, Sebastian Riedel, Antonio Frontera, Jan Lundell, Kari Rissanen
Format: Article
Language:English
Published: Nature Portfolio 2025-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-62191-1
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