Insights into the Factors Controlling the Origin of Activation Barriers in the [2 + 2] Cycloaddition Reactions of Heavy Imine-like Molecules Featuring a Ge=Group 15 Double Bond with Heterocumulenes

Insights into the Factors Controlling the Origin of Activation Barriers in the [2 + 2] Cycloaddition Reactions of Heavy Imine-like Molecules Featuring a Ge=Group 15 Double Bond with Heterocumulenes

The [2 + 2] cycloaddition reactions of the heterocumulene (<b>N=C=N</b>) with the heavy imine-like molecule <b>Ge=G15-Rea</b> (G15 = Group 15 element) were examined using density functional theory (M06-2X-D3/def2-TZVP). The theoretical findings indicate that the doubly bonded...

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Bibliographic Details
Main Authors: Zheng-Feng Zhang, Ming-Der Su
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Molecules
Subjects:
[2 + 2] cycloaddition
heterocumulene
heavy imine
donor–acceptor interaction
electron-sharing
Online Access:https://www.mdpi.com/1420-3049/30/9/1905
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