Water-controlled skeletal editing or peripheral modification of ortho-chalcone-substituted organophosphines

Water-controlled skeletal editing or peripheral modification of ortho-chalcone-substituted organophosphines

Skeletal editing of organophosphines is highly challenging owing to the high P-C bond dissociation energy. Herein, we report an efficient catalyst- and additive-free skeletal editing strategy to transform easily accessible ortho-chalcone based organophosphines into new and complex phosphine oxides,...

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Bibliographic Details
Main Authors: Xin-Yue Niu, Chao-Yang Li, Cong-Cong Zhang, Zhan-Wei Bu, Yan Xie, Wen-Jing Zhang, Qi-Lin Wang
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2025-05-01
Series:Green Synthesis and Catalysis
Subjects:
Skeletal editing
Peripheral modification
Organophosphines
Divergent synthesis
DFT calculations
Online Access:http://www.sciencedirect.com/science/article/pii/S2666554923001084
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http://www.sciencedirect.com/science/article/pii/S2666554923001084

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