Photolytic activation of Ni(II)X2L explains how Ni-mediated cross coupling begins

Photolytic activation of Ni(II)X2L explains how Ni-mediated cross coupling begins

Abstract Nickel photocatalysis has recently become vital to organic synthesis, but how the Ni(II)X2L pre-catalyst (X = Cl, Br; L = bidentate ligand) becomes activated to Ni(I)XL has remained puzzling and is typically addressed on a case-by-case basis. Here, we reveal a general mechanism where light...

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Main Authors: Max Kudisch, Reagan X. Hooper, Lakshmy K. Valloli, Justin D. Earley, Anna Zieleniewska, Jin Yu, Stephen DiLuzio, Rebecca W. Smaha, Hannah Sayre, Xiaoyi Zhang, Matthew J. Bird, Amy A. Cordones, Garry Rumbles, Obadiah G. Reid
Format: Article
Language:English
Published: Nature Portfolio 2025-07-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-60729-x
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https://doi.org/10.1038/s41467-025-60729-x

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