The Study of Thermal Decomposition of Natural Calcium Carbonate by the Temperature-programmed Mass Spectrometry Technique
The experiments have shown that the heating range for quantitative evolution of carbon dioxide gas (CO2) from natural calcium carbonates (e.g., chalk, corals, shells of the Anadara clams (Anadara inaequivalvis), shell of bird eggs) is from 500 to 850 C with a total heating time of 30-50 minutes. Th...
Saved in:
| Main Authors: | , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Sumy State University
2016-11-01
|
| Series: | Журнал нано- та електронної фізики |
| Subjects: | |
| Online Access: | http://jnep.sumdu.edu.ua/download/numbers/2016/4/articles/jnep_2016_V8_04031.pdf |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849737217135607808 |
|---|---|
| author | S.N. Danilchenko V.D. Chіvanov A.G. Ryabishev S.V. Novіkov A.A. Stepanenko V.N. Kuznetsov E.V. Mironets A.V. Marіychuk A.A. Yanovska O.G. Bordunova A.N. Bugay |
| author_facet | S.N. Danilchenko V.D. Chіvanov A.G. Ryabishev S.V. Novіkov A.A. Stepanenko V.N. Kuznetsov E.V. Mironets A.V. Marіychuk A.A. Yanovska O.G. Bordunova A.N. Bugay |
| author_sort | S.N. Danilchenko |
| collection | DOAJ |
| description | The experiments have shown that the heating range for quantitative evolution of carbon dioxide gas (CO2) from natural calcium carbonates (e.g., chalk, corals, shells of the Anadara clams (Anadara inaequivalvis), shell of bird eggs) is from 500 to 850 C with a total heating time of 30-50 minutes. The only exception is the sample of a mortar from a masonry of Saint Sophia Cathedral (the architectural monument of XI century), in which the lowest border of the heating range for carbon dioxide evolution is 400 C. The shape of the CO2 evolution curves for every sample is significantly different in width and intensity as compared to the standard sample (chemically pure synthetic CaCO3). The results, which were obtained on the thermoprogrammed mass-spectrometry (TP‑MS) unit, designed and produced by the authors of the current paper, are of great importance for the development of a gas input technique for radiocarbon dating with accelerator mass-spectrometry. |
| format | Article |
| id | doaj-art-85fdabb90aa84bd9bba7fdcb46047b8a |
| institution | DOAJ |
| issn | 2077-6772 |
| language | English |
| publishDate | 2016-11-01 |
| publisher | Sumy State University |
| record_format | Article |
| series | Журнал нано- та електронної фізики |
| spelling | doaj-art-85fdabb90aa84bd9bba7fdcb46047b8a2025-08-20T03:07:00ZengSumy State UniversityЖурнал нано- та електронної фізики2077-67722016-11-018404031-104031-310.21272/jnep.8(4(1)).04031The Study of Thermal Decomposition of Natural Calcium Carbonate by the Temperature-programmed Mass Spectrometry TechniqueS.N. Danilchenko0V.D. Chіvanov1A.G. Ryabishev2S.V. Novіkov3A.A. Stepanenko4V.N. Kuznetsov5E.V. Mironets6A.V. Marіychuk7A.A. Yanovska8O.G. Bordunova9A.N. Bugay10Institute of Applied Physics NASU, 58, Petropavlovskaya st., 40000 Sumy, UkraineInstitute of Applied Physics NASU, 58, Petropavlovskaya st., 40000 Sumy, UkraineInstitute of Applied Physics NASU, 58, Petropavlovskaya st., 40000 Sumy, UkraineInstitute of Applied Physics NASU, 58, Petropavlovskaya st., 40000 Sumy, UkraineSumy State University, 2, Rimsky Korsakov st., 40007 Sumy, UkraineInstitute of Applied Physics NASU, 58, Petropavlovskaya st., 40000 Sumy, UkraineInstitute of Applied Physics NASU, 58, Petropavlovskaya st., 40000 Sumy, UkraineInstitute of Applied Physics NASU, 58, Petropavlovskaya st., 40000 Sumy, UkraineInstitute of Applied Physics NASU, 58, Petropavlovskaya st., 40000 Sumy, UkraineSumy National Agrarian University, 160, Gerasim Kondratyev st., 40021 Sumy, UkraineInstitute of Applied Physics NASU, 58, Petropavlovskaya st., 40000 Sumy, UkraineThe experiments have shown that the heating range for quantitative evolution of carbon dioxide gas (CO2) from natural calcium carbonates (e.g., chalk, corals, shells of the Anadara clams (Anadara inaequivalvis), shell of bird eggs) is from 500 to 850 C with a total heating time of 30-50 minutes. The only exception is the sample of a mortar from a masonry of Saint Sophia Cathedral (the architectural monument of XI century), in which the lowest border of the heating range for carbon dioxide evolution is 400 C. The shape of the CO2 evolution curves for every sample is significantly different in width and intensity as compared to the standard sample (chemically pure synthetic CaCO3). The results, which were obtained on the thermoprogrammed mass-spectrometry (TP‑MS) unit, designed and produced by the authors of the current paper, are of great importance for the development of a gas input technique for radiocarbon dating with accelerator mass-spectrometry.http://jnep.sumdu.edu.ua/download/numbers/2016/4/articles/jnep_2016_V8_04031.pdfTemperature programmed mass spectrometry (MS‑TP)Calcium carbonateCarbon dioxid |
| spellingShingle | S.N. Danilchenko V.D. Chіvanov A.G. Ryabishev S.V. Novіkov A.A. Stepanenko V.N. Kuznetsov E.V. Mironets A.V. Marіychuk A.A. Yanovska O.G. Bordunova A.N. Bugay The Study of Thermal Decomposition of Natural Calcium Carbonate by the Temperature-programmed Mass Spectrometry Technique Журнал нано- та електронної фізики Temperature programmed mass spectrometry (MS‑TP) Calcium carbonate Carbon dioxid |
| title | The Study of Thermal Decomposition of Natural Calcium Carbonate by the Temperature-programmed Mass Spectrometry Technique |
| title_full | The Study of Thermal Decomposition of Natural Calcium Carbonate by the Temperature-programmed Mass Spectrometry Technique |
| title_fullStr | The Study of Thermal Decomposition of Natural Calcium Carbonate by the Temperature-programmed Mass Spectrometry Technique |
| title_full_unstemmed | The Study of Thermal Decomposition of Natural Calcium Carbonate by the Temperature-programmed Mass Spectrometry Technique |
| title_short | The Study of Thermal Decomposition of Natural Calcium Carbonate by the Temperature-programmed Mass Spectrometry Technique |
| title_sort | study of thermal decomposition of natural calcium carbonate by the temperature programmed mass spectrometry technique |
| topic | Temperature programmed mass spectrometry (MS‑TP) Calcium carbonate Carbon dioxid |
| url | http://jnep.sumdu.edu.ua/download/numbers/2016/4/articles/jnep_2016_V8_04031.pdf |
| work_keys_str_mv | AT sndanilchenko thestudyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT vdchívanov thestudyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT agryabishev thestudyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT svnovíkov thestudyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT aastepanenko thestudyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT vnkuznetsov thestudyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT evmironets thestudyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT avmaríychuk thestudyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT aayanovska thestudyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT ogbordunova thestudyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT anbugay thestudyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT sndanilchenko studyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT vdchívanov studyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT agryabishev studyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT svnovíkov studyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT aastepanenko studyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT vnkuznetsov studyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT evmironets studyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT avmaríychuk studyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT aayanovska studyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT ogbordunova studyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique AT anbugay studyofthermaldecompositionofnaturalcalciumcarbonatebythetemperatureprogrammedmassspectrometrytechnique |