L’anion fluorure comme base en synthèse organique: methylénation des cycloalcanediols-1,2 par le dichlorométhane; nouvelle méthode de préparation des diméthylène-2,3 norbornanes
1,2-cycloalcanediols heated in CH2Cl2/DMF (or DMSO) containing an excess of CsF furnish the corresponding 1,3-dioxolanes when the hydroxyl groups are in a cis-eclipsed conformation. This technique can be applied to sensitive diols (e. g. 5,6-dimethylidene- exo,exo-2,3-norbornanediol) that are not c...
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| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1977-04-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9346 |
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