Influence of Electron Transfer Mediators in the Pd(II)-Catalyzed Oxidative Carbonylation of Aniline

Influence of Electron Transfer Mediators in the Pd(II)-Catalyzed Oxidative Carbonylation of Aniline

Currently, the most promising alternative to the use of the phosgenation reaction, for large-scale production of isocyanates, ureas, and carbamates, appears to be the Pd-catalyzed oxidative carbonylation of arylamines. During the reaction, the Pd(II) catalytic species are reduced to Pd(0) and the ad...

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Bibliographic Details
Main Authors: Andrea Vavasori, Lucio Ronchin, Luca Pietrobon, Sara Bravo
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Molecules
Subjects:
oxidative carbonylation
palladium catalyst
electron transfer mediator
phenyl isocyanate
1,3–diphenylurea
Online Access:https://www.mdpi.com/1420-3049/30/9/2027
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