Stereochemistry of the Diels-Alder Addition of Halogenated Cyclopropenes
The structures of two cycloadducts (1 and 2) of cyclopropenes to 1,3-diphenyl-isobenzofuran and trans-1-phenylbutadiene are established by X-ray crystallography. Both are exo adducts. In 2 the phenyl substituent occupies a pseudo-axial position; the ring-flipped conformation (2a) with the phenyl ri...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1987-08-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9802 |
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