Preparation of Nickel Nanocatalysts and Application to the Hydrodechlorination of 3-Chlorophenol under Liquid Phase
Nickel nanoparticles were successfully synthesized via the reduction of nickel salt using ethylene glycol (EG) and sodium borohydride (NaBH4) as reducing agents. These nickel nanoparticles were then loaded on the supports as Ni-X (X = vanadium phosphorus oxides (VPO), TiO2, and ZnO) in high loading...
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| Format: | Article |
| Language: | English |
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Wiley
2021-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2021/8580754 |
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| author | Thanh Thien Co Thi Kim Anh Tran Thi Huong Ly Doan Thi Duyen Diep |
| author_facet | Thanh Thien Co Thi Kim Anh Tran Thi Huong Ly Doan Thi Duyen Diep |
| author_sort | Thanh Thien Co |
| collection | DOAJ |
| description | Nickel nanoparticles were successfully synthesized via the reduction of nickel salt using ethylene glycol (EG) and sodium borohydride (NaBH4) as reducing agents. These nickel nanoparticles were then loaded on the supports as Ni-X (X = vanadium phosphorus oxides (VPO), TiO2, and ZnO) in high loading yield. The optical properties of these catalysts were characterized by UV-vis spectroscopy, the structure of Ni-X was studied by powder X-ray diffraction (PXRD), the distribution of Ni particles in X was studied by transmission electron microscopy (TEM), and the specific surface area of Ni-X was evaluated by N2 adsorption isotherm analysis at 77 K. All results corroborated the loading process. Indeed, TEM image indicated that the nickel nanoparticles size is in the range of 14 ÷ 16 nm and fully loaded into X. The activities of these catalysts were performed on the hydrodechlorination of 3-chlorophenol in the presence of sodium hydroxide as base at atmospheric pressure and at RT. The results showed that Ni-X exhibited high activities up to 98% within 90 min in the case of Ni-ZnO catalyst. |
| format | Article |
| id | doaj-art-7ebd6923dc6245b69f2f4dbcb62ea1e2 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2021-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-7ebd6923dc6245b69f2f4dbcb62ea1e22025-02-03T01:25:41ZengWileyJournal of Chemistry2090-90632090-90712021-01-01202110.1155/2021/85807548580754Preparation of Nickel Nanocatalysts and Application to the Hydrodechlorination of 3-Chlorophenol under Liquid PhaseThanh Thien Co0Thi Kim Anh Tran1Thi Huong Ly Doan2Thi Duyen Diep3University of Science, Ho Chi Minh City, VietnamUniversity of Science, Ho Chi Minh City, VietnamUniversity of Science, Ho Chi Minh City, VietnamUniversity of Science, Ho Chi Minh City, VietnamNickel nanoparticles were successfully synthesized via the reduction of nickel salt using ethylene glycol (EG) and sodium borohydride (NaBH4) as reducing agents. These nickel nanoparticles were then loaded on the supports as Ni-X (X = vanadium phosphorus oxides (VPO), TiO2, and ZnO) in high loading yield. The optical properties of these catalysts were characterized by UV-vis spectroscopy, the structure of Ni-X was studied by powder X-ray diffraction (PXRD), the distribution of Ni particles in X was studied by transmission electron microscopy (TEM), and the specific surface area of Ni-X was evaluated by N2 adsorption isotherm analysis at 77 K. All results corroborated the loading process. Indeed, TEM image indicated that the nickel nanoparticles size is in the range of 14 ÷ 16 nm and fully loaded into X. The activities of these catalysts were performed on the hydrodechlorination of 3-chlorophenol in the presence of sodium hydroxide as base at atmospheric pressure and at RT. The results showed that Ni-X exhibited high activities up to 98% within 90 min in the case of Ni-ZnO catalyst.http://dx.doi.org/10.1155/2021/8580754 |
| spellingShingle | Thanh Thien Co Thi Kim Anh Tran Thi Huong Ly Doan Thi Duyen Diep Preparation of Nickel Nanocatalysts and Application to the Hydrodechlorination of 3-Chlorophenol under Liquid Phase Journal of Chemistry |
| title | Preparation of Nickel Nanocatalysts and Application to the Hydrodechlorination of 3-Chlorophenol under Liquid Phase |
| title_full | Preparation of Nickel Nanocatalysts and Application to the Hydrodechlorination of 3-Chlorophenol under Liquid Phase |
| title_fullStr | Preparation of Nickel Nanocatalysts and Application to the Hydrodechlorination of 3-Chlorophenol under Liquid Phase |
| title_full_unstemmed | Preparation of Nickel Nanocatalysts and Application to the Hydrodechlorination of 3-Chlorophenol under Liquid Phase |
| title_short | Preparation of Nickel Nanocatalysts and Application to the Hydrodechlorination of 3-Chlorophenol under Liquid Phase |
| title_sort | preparation of nickel nanocatalysts and application to the hydrodechlorination of 3 chlorophenol under liquid phase |
| url | http://dx.doi.org/10.1155/2021/8580754 |
| work_keys_str_mv | AT thanhthienco preparationofnickelnanocatalystsandapplicationtothehydrodechlorinationof3chlorophenolunderliquidphase AT thikimanhtran preparationofnickelnanocatalystsandapplicationtothehydrodechlorinationof3chlorophenolunderliquidphase AT thihuonglydoan preparationofnickelnanocatalystsandapplicationtothehydrodechlorinationof3chlorophenolunderliquidphase AT thiduyendiep preparationofnickelnanocatalystsandapplicationtothehydrodechlorinationof3chlorophenolunderliquidphase |