Nucleophilic Addition Reactions to 10-Acetonitrilium Derivative of <i>nido</i>-Carborane and Intramolecular NH⋯HB Interactions in <i>N</i>-Alkyl Amidines 10-RNHC(Me)=NH-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>11</sub>

Nucleophilic Addition Reactions to 10-Acetonitrilium Derivative of <i>nido</i>-Carborane and Intramolecular NH⋯HB Interactions in <i>N</i>-Alkyl Amidines 10-RNHC(Me)=NH-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>11</sub>

The addition reactions of water, alcohols, and primary and secondary amines to the 10-acetonitrilium derivative of <i>nido</i>-carborane were studied. Hydrolysis of 10-MeC≡N-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>11</sub> results in iminol 10-MeC(OH)=HN-7...

Full description

Saved in:
Bibliographic Details
Main Authors: Kirill R. Pakholkov, Ekaterina V. Bogdanova, Marina Yu. Stogniy, Kyrill Yu. Suponitsky, Sergey A. Anufriev, Igor B. Sivaev, Vladimir I. Bregadze
Format: Article
Language:English
Published: MDPI AG 2025-02-01
Series:Molecules
Subjects:
<i>nido</i>-carborane
acetonitrilium derivative
amide
iminol
imidates
amidines
Online Access:https://www.mdpi.com/1420-3049/30/4/828
Tags: Add Tag
No Tags, Be the first to tag this record!

Internet

https://www.mdpi.com/1420-3049/30/4/828

Similar Items