Synthesis of β-ketophosphonates through aerobic copper(II)-mediated phosphorylation of enol acetates

Synthesis of β-ketophosphonates through aerobic copper(II)-mediated phosphorylation of enol acetates

Aerobic copper(II)-mediated phosphorylation of enol acetates with H-phosphonates leading to the formation of β-ketophosphonates was discovered. The proposed method is applicable to a wide range of H-phosphonates or phosphine oxides as PH-reagents and enol acetates. Unlike previous reports, which gen...

Full description

Saved in:
Bibliographic Details
Main Authors: Alexander S. Budnikov, Igor B. Krylov, Fedor K. Monin, Valentina M. Merkulova, Alexey I. Ilovaisky, Liu Yan, Bing Yu, Alexander O. Terent’ev
Format: Article
Language:English
Published: Beilstein-Institut 2025-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
c–p coupling
copper
enol acetates
β-ketophosphonates
phosphorylation
Online Access:https://doi.org/10.3762/bjoc.21.96
Tags: Add Tag
No Tags, Be the first to tag this record!

Internet

https://doi.org/10.3762/bjoc.21.96

Similar Items