Microencapsulation of Extracts of Strawberry (<i>Fragaria vesca</i>) By-Products by Spray-Drying Using Individual and Binary/Ternary Blends of Biopolymers

Valorization of agricultural and food by-products (agri-food waste) and maximum utilization of this raw material constitute a highly relevant topic worldwide. Agri-food waste contains different types of phytochemical compounds such as polyphenols, that display a set of biological properties, includi...

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Main Authors: Yara Bastos, Fernando Rocha, Berta Nogueiro Estevinho
Format: Article
Language:English
Published: MDPI AG 2024-09-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/29/19/4528
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author Yara Bastos
Fernando Rocha
Berta Nogueiro Estevinho
author_facet Yara Bastos
Fernando Rocha
Berta Nogueiro Estevinho
author_sort Yara Bastos
collection DOAJ
description Valorization of agricultural and food by-products (agri-food waste) and maximum utilization of this raw material constitute a highly relevant topic worldwide. Agri-food waste contains different types of phytochemical compounds such as polyphenols, that display a set of biological properties, including anti-inflammatory, chemo-preventive, and immune-stimulating effects. In this work, the microencapsulation of strawberry (<i>Fragaria vesca</i>) plant extract was made by spray-drying using individual biopolymers, as well as binary and ternary blends of pectin, alginate, and carrageenan. The microparticle morphologies depended on the formulation used, and they had an average size between 0.01 μm and 16.3 μm considering a volume size distribution. The encapsulation efficiency ranged between 81 and 100%. The kinetic models of Korsmeyer–Peppas (R<sup>2</sup>: 0.35–0.94) and Baker–Lonsdale (R<sup>2</sup>: 0.73–1.0) were fitted to the experimental release profiles. In general, the releases followed a “Fickian Diffusion” mechanism, with total release times varying between 100 and 350 (ternary blends) seconds. The microparticles containing only quercetin (one of the main polyphenols in the plant) showed higher antioxidant power compared to the extract and empty particles. Finally, the addition of the different types of microparticles to the gelatine (2.7 mPa.s) and to the aloe vera gel (640 mPa.s) provoked small changes in the viscosity of the final gelatine (2.3 and 3.3 mPa.s) and of the aloe vera gel (621–653 mPa.s). At a visual level, it is possible to conclude that in the gelatine matrix, there was a slight variation in color, while in the aloe vera gel, no changes were registered. In conclusion, these microparticles present promising characteristics for food, nutraceutical, and cosmetic applications.
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spelling doaj-art-7480b7582ff74fa9b898c34821b69f422025-08-20T02:16:54ZengMDPI AGMolecules1420-30492024-09-012919452810.3390/molecules29194528Microencapsulation of Extracts of Strawberry (<i>Fragaria vesca</i>) By-Products by Spray-Drying Using Individual and Binary/Ternary Blends of BiopolymersYara Bastos0Fernando Rocha1Berta Nogueiro Estevinho2LEPABE—Laboratory for Process Engineering, Environment, Biotechnology and Energy, Department of Chemical Engineer, Faculty of Engineer, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, PortugalLEPABE—Laboratory for Process Engineering, Environment, Biotechnology and Energy, Department of Chemical Engineer, Faculty of Engineer, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, PortugalLEPABE—Laboratory for Process Engineering, Environment, Biotechnology and Energy, Department of Chemical Engineer, Faculty of Engineer, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, PortugalValorization of agricultural and food by-products (agri-food waste) and maximum utilization of this raw material constitute a highly relevant topic worldwide. Agri-food waste contains different types of phytochemical compounds such as polyphenols, that display a set of biological properties, including anti-inflammatory, chemo-preventive, and immune-stimulating effects. In this work, the microencapsulation of strawberry (<i>Fragaria vesca</i>) plant extract was made by spray-drying using individual biopolymers, as well as binary and ternary blends of pectin, alginate, and carrageenan. The microparticle morphologies depended on the formulation used, and they had an average size between 0.01 μm and 16.3 μm considering a volume size distribution. The encapsulation efficiency ranged between 81 and 100%. The kinetic models of Korsmeyer–Peppas (R<sup>2</sup>: 0.35–0.94) and Baker–Lonsdale (R<sup>2</sup>: 0.73–1.0) were fitted to the experimental release profiles. In general, the releases followed a “Fickian Diffusion” mechanism, with total release times varying between 100 and 350 (ternary blends) seconds. The microparticles containing only quercetin (one of the main polyphenols in the plant) showed higher antioxidant power compared to the extract and empty particles. Finally, the addition of the different types of microparticles to the gelatine (2.7 mPa.s) and to the aloe vera gel (640 mPa.s) provoked small changes in the viscosity of the final gelatine (2.3 and 3.3 mPa.s) and of the aloe vera gel (621–653 mPa.s). At a visual level, it is possible to conclude that in the gelatine matrix, there was a slight variation in color, while in the aloe vera gel, no changes were registered. In conclusion, these microparticles present promising characteristics for food, nutraceutical, and cosmetic applications.https://www.mdpi.com/1420-3049/29/19/4528add-value productsagri-food wasteantioxidantscircular economycosmetic applicationfood products
spellingShingle Yara Bastos
Fernando Rocha
Berta Nogueiro Estevinho
Microencapsulation of Extracts of Strawberry (<i>Fragaria vesca</i>) By-Products by Spray-Drying Using Individual and Binary/Ternary Blends of Biopolymers
Molecules
add-value products
agri-food waste
antioxidants
circular economy
cosmetic application
food products
title Microencapsulation of Extracts of Strawberry (<i>Fragaria vesca</i>) By-Products by Spray-Drying Using Individual and Binary/Ternary Blends of Biopolymers
title_full Microencapsulation of Extracts of Strawberry (<i>Fragaria vesca</i>) By-Products by Spray-Drying Using Individual and Binary/Ternary Blends of Biopolymers
title_fullStr Microencapsulation of Extracts of Strawberry (<i>Fragaria vesca</i>) By-Products by Spray-Drying Using Individual and Binary/Ternary Blends of Biopolymers
title_full_unstemmed Microencapsulation of Extracts of Strawberry (<i>Fragaria vesca</i>) By-Products by Spray-Drying Using Individual and Binary/Ternary Blends of Biopolymers
title_short Microencapsulation of Extracts of Strawberry (<i>Fragaria vesca</i>) By-Products by Spray-Drying Using Individual and Binary/Ternary Blends of Biopolymers
title_sort microencapsulation of extracts of strawberry i fragaria vesca i by products by spray drying using individual and binary ternary blends of biopolymers
topic add-value products
agri-food waste
antioxidants
circular economy
cosmetic application
food products
url https://www.mdpi.com/1420-3049/29/19/4528
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