Enantioselective acyl-trifluoromethylation of olefins by bulky thiazolium carbene catalysis

Abstract Enantioenriched α-chiral β-fluorinated ketones are valuable structural motifs with application in several fields. The recently emerged concept of NHC-catalyzed radical acyl-trifluoromethylation of olefins offers a rapid route to construct racemic β-fluorinated ketones in a single step. Due...

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Bibliographic Details
Main Authors: Sripati Jana, Matthew D. Wodrich, Nicolai Cramer
Format: Article
Language:English
Published: Nature Portfolio 2025-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-58423-z
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