Well-Dispersed Silica Fume by Surface Modification and the Control of Cement Hydration

Silica fume (SF) is a valuable nanoscaled industrial by-product used in cementitious materials owing to its filling and pozzolanic effect. However, the heavy agglomeration of SF is a severe and common problem. In this study, surface modification with polyacrylic acid (PAA) was applied on SF to achie...

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Main Authors: Rui Ma, Liping Guo, Wei Sun, Zhidan Rong
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Advances in Civil Engineering
Online Access:http://dx.doi.org/10.1155/2018/6184105
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author Rui Ma
Liping Guo
Wei Sun
Zhidan Rong
author_facet Rui Ma
Liping Guo
Wei Sun
Zhidan Rong
author_sort Rui Ma
collection DOAJ
description Silica fume (SF) is a valuable nanoscaled industrial by-product used in cementitious materials owing to its filling and pozzolanic effect. However, the heavy agglomeration of SF is a severe and common problem. In this study, surface modification with polyacrylic acid (PAA) was applied on SF to achieve a better dispersion and to optimize the hydration process of cement at early age. The particle size distribution and surface properties of SF, as well as the cement hydration with modified SF, were investigated. The results demonstrated that the agglomeration of SF particles was efficiently mitigated by the surface treatment with PAA, and the acceleration effect of SF was delayed by the resistance of the surface layer at early age. However, the grafted PAA layer eventually dropped in alkali solution after 6 hours, and the hydration rate was increased again and continued for long time. This work indicated that surface-modified SF was well dispersed and was able to regulate the hydration rate of cement.
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institution Kabale University
issn 1687-8086
1687-8094
language English
publishDate 2018-01-01
publisher Wiley
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series Advances in Civil Engineering
spelling doaj-art-6d902d01f1d04c4d9c0c1b46e9a2e2ac2025-02-03T01:13:00ZengWileyAdvances in Civil Engineering1687-80861687-80942018-01-01201810.1155/2018/61841056184105Well-Dispersed Silica Fume by Surface Modification and the Control of Cement HydrationRui Ma0Liping Guo1Wei Sun2Zhidan Rong3School of Materials Science and Engineering, Southeast University, Nanjing 211189, ChinaSchool of Materials Science and Engineering, Southeast University, Nanjing 211189, ChinaSchool of Materials Science and Engineering, Southeast University, Nanjing 211189, ChinaSchool of Materials Science and Engineering, Southeast University, Nanjing 211189, ChinaSilica fume (SF) is a valuable nanoscaled industrial by-product used in cementitious materials owing to its filling and pozzolanic effect. However, the heavy agglomeration of SF is a severe and common problem. In this study, surface modification with polyacrylic acid (PAA) was applied on SF to achieve a better dispersion and to optimize the hydration process of cement at early age. The particle size distribution and surface properties of SF, as well as the cement hydration with modified SF, were investigated. The results demonstrated that the agglomeration of SF particles was efficiently mitigated by the surface treatment with PAA, and the acceleration effect of SF was delayed by the resistance of the surface layer at early age. However, the grafted PAA layer eventually dropped in alkali solution after 6 hours, and the hydration rate was increased again and continued for long time. This work indicated that surface-modified SF was well dispersed and was able to regulate the hydration rate of cement.http://dx.doi.org/10.1155/2018/6184105
spellingShingle Rui Ma
Liping Guo
Wei Sun
Zhidan Rong
Well-Dispersed Silica Fume by Surface Modification and the Control of Cement Hydration
Advances in Civil Engineering
title Well-Dispersed Silica Fume by Surface Modification and the Control of Cement Hydration
title_full Well-Dispersed Silica Fume by Surface Modification and the Control of Cement Hydration
title_fullStr Well-Dispersed Silica Fume by Surface Modification and the Control of Cement Hydration
title_full_unstemmed Well-Dispersed Silica Fume by Surface Modification and the Control of Cement Hydration
title_short Well-Dispersed Silica Fume by Surface Modification and the Control of Cement Hydration
title_sort well dispersed silica fume by surface modification and the control of cement hydration
url http://dx.doi.org/10.1155/2018/6184105
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AT zhidanrong welldispersedsilicafumebysurfacemodificationandthecontrolofcementhydration