Bis(μ-thiosemicarbazide-κ3N1,S:S;κ3S:N1,S)bis[(dimethylformamide-κO)(thiosemicarbazide-κ2N1,S)cadmium(II)] tetrakis(2,4,6-trinitrophenolate): synthesis, crystal structure and Hirshfeld surface analysis

Bis(μ-thiosemicarbazide-κ3N1,S:S;κ3S:N1,S)bis[(dimethylformamide-κO)(thiosemicarbazide-κ2N1,S)cadmium(II)] tetrakis(2,4,6-trinitrophenolate): synthesis, crystal structure and Hirshfeld surface analysis

In the title complex salt, [Cd2(C3H7NO)2(CH5N3S)4](C6H2N3O7)4, (I), the binuclear cation is located about a crystallographic center of symmetry. The asymmetric unit of the complex cation is composed of two bidentate thiosemicarbazide ligands and one molecule of dimethylformamide coordinated to a cad...

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Bibliographic Details
Main Authors: R. Santhakumari, K. Ramamurthi, Manpreet Kaur, Jerry P. Jasinski, Suresh Sagadevan, Helen Stoeckli-Evans
Format: Article
Language:English
Published: International Union of Crystallography 2025-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cadmium complex
thiosemicarbazide
picrate
hydrogen bonding
hirshfeld surface
fingerprint plots
Online Access:https://journals.iucr.org/paper?S2056989025003974
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