Ring Tension, Hydrocarbon Acidity, and New «Super-Bases»

Addition of disodium pinacolate or, particularly, potassium tert-butoxide considerably increases the transmetalating power of pentylsodium. A hexane slurry of such «NACNAOR» or «NACKOR» reagent mixtures readily and selectively converts 3,3-dimenthyl-1-butene, camphene, bicyclo[2.2.2]oct-2-ene, and...

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Bibliographic Details
Main Authors: Manfred Schlosser, Jürgen Hartmann, Manfred Stähle, Jaroslav Kramař, Annelies Walde, Alessandro Mordini
Format: Article
Language:deu
Published: Swiss Chemical Society 1986-09-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9745
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